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Intensive properties are material characteristics and are not dependent on the size or extent of the sample. Commonly quoted and tabulated in the literature are the specific latent heat of fusion and the specific latent heat of vaporization for many substances. From this definition, the latent heat for a given mass of a substance is calculated by
The energy needed to evaporate the water is taken from the air in the form of sensible heat and converted into latent heat, while the air remains at a constant enthalpy. Latent heat describes the amount of heat that is needed to evaporate the liquid; this heat comes from the liquid itself and the surrounding gas and surfaces.
The caloric theory is an obsolete scientific theory that heat consists of a self-repellent fluid called caloric that flows from hotter bodies to colder bodies. Caloric was also thought of as a weightless gas that could pass in and out of pores in solids and liquids.
Calorimetry requires that a reference material that changes temperature have known definite thermal constitutive properties. The classical rule, recognized by Clausius and Kelvin, is that the pressure exerted by the calorimetric material is fully and rapidly determined solely by its temperature and volume; this rule is for changes that do not involve phase change, such as melting of ice.
In a statistical mechanical account of an ideal gas, in which the molecules move independently between instantaneous collisions, the internal energy is just the sum total of the gas's independent particles' kinetic energies, and it is this kinetic motion that is the source and the effect of the transfer of heat across a system's boundary.
For 0 < α < 1, the heat capacity diverges at the transition temperature (though, since α < 1, the enthalpy stays finite). An example of such behavior is the 3D ferromagnetic phase transition. In the three-dimensional Ising model for uniaxial magnets, detailed theoretical studies have yielded the exponent α ≈ +0.110.
Summer 2023 saw record-breaking heat, and, according to the Centers of Disease Control and Prevention, 90% of the 120,000 heat-related emergency room visits in the United States last year took ...
A representation of Hess's law (where H represents enthalpy) Hess's law of constant heat summation, also known simply as Hess's law, is a relationship in physical chemistry and thermodynamics [1] named after Germain Hess, a Swiss-born Russian chemist and physician who published it in 1840.