Search results
Results from the WOW.Com Content Network
Lithium chloride is a chemical compound with the formula Li Cl.The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li + ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.
This is a list of CAS numbers by chemical formulas and chemical compounds, ... (NO 3) 3: aluminium nitrate: 13473–90–0 Al ... LiCl: lithium chloride: 7447–41–8
Solubility of LiCl in various solvents (g LiCl / 100g of solvent at 25 °C) H 2 O: 84.5 Liquid ammonia: 3.02 Liquid sulfur dioxide: 0.012 Methanol: 21 - 41 Formic acid: 27.5 Sulfolane: 1.5 Acetonitrile: 0.14 Acetone: 0.83 Formamide: 28.2 Dimethylformamide: 11 - 28 Reference: Burgess, J. Metal Ions in Solution (Ellis Horwood, New York, 1978 ...
Addition of one equivalent of LiCl to isopropylmagnesium chloride gives "Turbo Grignard" solutions, named so due to the increased rate and efficiency for transmetalation reactions. [4] [5] Isopropylmagnesium chloride is also used to prepare isopropyl compounds, such as chlorodiisopropylphosphine: [6] PCl 3 + 2 (CH 3) 2 CHMgCl → [(CH 3) 2 CH ...
3 Cl 2 + 6 LiOH → 5 LiCl + LiClO 3 + 3 H 2 O. Lithium chlorate has one of the highest solubilities in water for a chemical compound. It is also a six-electron oxidant. Its electrochemical reduction is facilitated by acid, electrocatalysts and redox mediators. These properties make lithium chlorate a useful oxidant for high energy density flow ...
iPr 2 NMgCl·LiCl and TMPMgCl·LiCl react differently. The TMP-Turbo-Hauser base easily metalates ethyl-3-chlorobenzoate in the C2 position, while the same reaction carried out with the iPr-Turbo-Hauser base resulted in no metalation at all. Instead, an addition-elimination reaction occurs. [4] Contrasting reactivity of iPr 2 NMgCl·LiCl and ...
Lithium perchlorate is also used as an electrolyte salt in lithium-ion batteries.Lithium perchlorate is chosen over alternative salts such as lithium hexafluorophosphate or lithium tetrafluoroborate when its superior electrical impedance, conductivity, hygroscopicity, and anodic stability properties are of importance to the specific application. [11]
The reverse, i.e., production of LAH from either sodium aluminium hydride or potassium aluminium hydride can be achieved by reaction with LiCl or lithium hydride in diethyl ether or THF: [44] NaAlH 4 + LiCl → LiAlH 4 + NaCl KAlH 4 + LiCl → LiAlH 4 + KCl "Magnesium alanate" (Mg(AlH 4) 2) arises similarly using MgBr 2: [45] 2 LiAlH 4 + MgBr 2 ...