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Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for separating and analyzing compounds that can be vaporized without decomposition. Typical uses of GC include testing the purity of a particular substance, or separating the different components of a mixture. [ 1 ]
Pyrolysis–gas chromatography–mass spectrometry is a method of chemical analysis in which the sample is heated to decomposition to produce smaller molecules that are separated by gas chromatography and detected using mass spectrometry. Pyrolysis is the thermal decomposition of materials in an inert atmosphere or a vacuum.
The mass spectrometry process normally requires a very pure sample while gas chromatography using a traditional detector (e.g. Flame ionization detector) cannot differentiate between multiple molecules that happen to take the same amount of time to travel through the column (i.e. have the same retention time), which results in two or more ...
Gas chromatography (GC) in combination with mass spectrometry is capable of separating isomeric compounds. Although GC has been successfully coupled to PTR-MS in the past, [20] this approach annihilates the real-time capability of the PTR-MS technology, because a single GC analysis run typically takes between 30 min and 1 h. Thus, state-of-the ...
Electron capture detector developed by James Lovelock in the Science Museum, London Electron capture detector, Science History Institute. The electron capture detector is used for detecting electron-absorbing components (high electronegativity) such as halogenated compounds in the output stream of a gas chromatograph.
gas chromatography Pyrolysis GC/MS chromatogram of mahogany wood analyzed with OpenChrom Pyrolysis–gas chromatography–mass spectrometry is a method of chemical analysis in which the sample is heated to decomposition to produce smaller molecules that are separated by gas chromatography and detected using mass spectrometry .
Comprehensive two-dimensional gas chromatography, or GC×GC, is a multidimensional gas chromatography technique that was originally described in 1984 by J. Calvin Giddings [1] and first successfully implemented in 1991 by John Phillips and his student Zaiyou Liu. [2] GC×GC utilizes two different columns with two different stationary phases. In ...
In mass spectrometry, direct analysis in real time (DART) is an ion source that produces electronically or vibronically excited-state species from gases such as helium, argon, or nitrogen that ionize atmospheric molecules or dopant molecules. The ions generated from atmospheric or dopant molecules undergo ion-molecule reactions with the sample ...