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Manganese(II) oxide is an inorganic compound with chemical formula MnO. [2] It forms green crystals. The compound is produced on a large scale as a component of fertilizers and food additives .
Manganese(II,III) oxide is the chemical compound with formula Mn 3 O 4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO · Mn 2 O 3 . Mn 3 O 4 is found in nature as the mineral hausmannite .
Examples include decomposition of hydrates such as ferric hydroxide to ferric oxide and water vapor, the decomposition of calcium carbonate to calcium oxide and carbon dioxide as well as iron carbonate to iron oxide: CaCO 3 → CaO + CO 2. Calcination processes are carried out in a variety of furnaces, including shaft furnaces, rotary kilns ...
Manganese may also form mixed oxides with other metals : Bixbyite, (Fe III,Mn III) 2 O 3, a manganese(III) iron(III) oxide mineral; Jacobsite, Mn II Fe III 2 O 4, a manganese(II) iron(III) oxide mineral; Columbite, (Fe II,Mn II)Nb 2 O 6, a niobate of iron(II) and manganese(II) Tantalite, (Fe II,Mn II)Ta 2 O 6, a tantalum(V) mineral group close ...
Manganese dioxide also catalyses the decomposition of hydrogen peroxide to oxygen and water: 2 H 2 O 2 → 2 H 2 O + O 2. Manganese dioxide decomposes above about 530 °C to manganese(III) oxide and oxygen. At temperatures close to 1000 °C, the mixed-valence compound Mn 3 O 4 forms. Higher temperatures give MnO, which is reduced only with ...
Lithium nickel manganese cobalt oxides (abbreviated NMC, Li-NMC, LNMC, or NCM) are mixed metal oxides of lithium, nickel, manganese and cobalt with the general formula LiNi x Mn y Co 1-x-y O 2. These materials are commonly used in lithium-ion batteries for mobile devices and electric vehicles , acting as the positively charged cathode .
The root of the word calcination refers to its most prominent use, which is to remove carbon from limestone (calcium carbonate) through combustion to yield calcium oxide (quicklime). This calcination reaction is CaCO 3 (s) → CaO(s) + CO 2 (g). Calcium oxide is a crucial ingredient in modern cement, and is also used as a chemical flux in smelting.
Manganese(IV) oxide was used in the original type of dry cell battery as an electron acceptor from zinc, and is the blackish material in carbon–zinc type flashlight cells. The manganese dioxide is reduced to the manganese oxide-hydroxide MnO(OH) during discharging, preventing the formation of hydrogen at the anode of the battery. [82]