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Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite . Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment.
The most common test (and used even today in water test kits) was discovered by Samuel Hahnemann. It would involve combining a sample fluid with hydrogen sulfide (H 2 S) in the presence of hydrochloric acid (HCl). A yellow precipitate, arsenic trisulfide (As 2 S 3) would be formed if arsenic was present. [6]
A C-119 Flying Boxcar, the type of plane used to release the chemicals. Operation LAC (Large Area Coverage) was a United States Army Chemical Corps operation which dispersed microscopic zinc cadmium sulfide (ZnCdS) particles over much of the United States and Canada in order to test dispersal patterns and the geographic range of chemical or biological weapons.
Sphalerite, which is a form of zinc sulfide, is the most heavily mined zinc-containing ore because its concentrate contains 60–62% zinc. [14] No significant deposits of cadmium-containing ores are known. Greenockite (CdS), the only cadmium mineral of importance, is nearly always associated with sphalerite (ZnS). This association is caused by ...
The reagent used can be any substance that gives S 2− ions in such solutions; most commonly used are hydrogen sulfide (at 0.2-0.3 M), thioacetamide (at 0.3-0.6 M), addition of hydrogen sulfide can often prove to be a lumbersome process and therefore sodium sulfide can also serve the purpose. The test with the sulfide ion must be conducted in ...
Sphalerite is an important ore of zinc; around 95% of all primary zinc is extracted from sphalerite ore. [42] However, due to its variable trace element content, sphalerite is also an important source of several other metals such as cadmium, [ 43 ] gallium, [ 44 ] germanium, [ 45 ] and indium [ 46 ] which replace zinc.
Zinc smelting is the process of converting zinc concentrates (ores that contain zinc) into pure zinc. Zinc smelting has historically been more difficult than the smelting of other metals, e.g. iron , because in contrast, zinc has a low boiling point .
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
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