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Cement: Calcium oxide is a key ingredient for the process of making cement. As a cheap and widely available alkali. About 50% of the total quicklime production is converted to calcium hydroxide before use. Both quick- and hydrated lime are used in the treatment of drinking water. [10]
So, CAC cement must not be confused with calcium sulfo-aluminate (CSA) cement containing calcium sulfate and invented later in 1936. [6] The main constituent, and also the most reactive phase, of calcium aluminate cements is the monocalcium aluminate (CaAl 2 O 4 = CaO · Al 2 O 3, also written as CA in the cement chemist notation).
The key chemical reaction distinguishing portland cement from other hydraulic limes occurs at these high temperatures (>1,300 °C (2,370 °F)) as belite (Ca 2 SiO 4) combines with calcium oxide (CaO) to form alite (Ca 3 SiO 5). [13]
Calcium aluminates phase diagram Crystal structure of dodecacalcium hepta-aluminate, 12CaO·7Al 2 O 3 (C 12 A 7). [1] Calcium aluminates are a range of materials [2] obtained by heating calcium oxide and aluminium oxide together at high temperatures. They are encountered in the manufacture of refractories and cements.
Calcium oxide is a crucial ingredient in modern cement, and is also used as a chemical flux in smelting. Industrial calcination generally emits carbon dioxide (CO 2 ). A calciner is a steel cylinder that rotates inside a heated furnace and performs indirect high-temperature processing (550–1150 °C, or 1000–2100 °F) within a controlled ...
Calcium aluminoferrite (Ca 2 (Al,Fe) 2 O 5) is a dark brown crystalline phase commonly found in cements. In the cement industry it is termed tetra-calcium aluminoferrite or ferrite. In cement chemist notation (CCN), it is abbreviated as C 4 AF meaning 4CaO· Al 2 O 3 · Fe 2 O 3 in the oxide notation. It also exists in nature as the rare ...
The cement chemist notation is not restricted to cement applications but is in fact a more general notation of oxide chemistry applicable to other domains than cement chemistry sensu stricto. For instance, in ceramics applications, the kaolinite formula can also be written in terms of oxides, thus the corresponding formula for kaolinite,
Tricalcium aluminate forms upon heating a 3:1 mixture of calcium oxide and aluminium oxide above 1300 °C. The crystals are cubic, with unit cell dimension 1.5263 nm [2] and has density 3064 kg·m −3. It melts with decomposition at 1542 °C.
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