Search results
Results from the WOW.Com Content Network
The mesomeric effect as a result of p-orbital overlap (resonance) has absolutely no effect on this inductive effect, as the inductive effect has purely to do with the electronegativity of the atoms and their topology in the molecule (which atoms are connected to which). Specifically the inductive effect is the tendency for the substituents to ...
The Mössbauer effect, or recoilless nuclear resonance fluorescence, is a physical phenomenon discovered by Rudolf Mössbauer in 1958. It involves the resonant and recoil -free emission and absorption of gamma radiation by atomic nuclei bound in a solid.
Helmholtz resonance, also known as wind throb, refers to the phenomenon of air resonance in a cavity, an effect named after the German physicist Hermann von Helmholtz. [1] This type of resonance occurs when air is forced in and out of a cavity (the resonance chamber), causing the air inside to vibrate at a specific natural frequency. The ...
The pEDA parameter (pi electron donor-acceptor) is a pi-electron substituent effect scale, described also as mesomeric or resonance effect. There is also a complementary scale - sEDA. The more positive is the value of pEDA the more pi-electron donating is a substituent.
In general, the resonance effect of elements in the third period and beyond is relatively weak. This is mainly because of the relatively poor orbital overlap of the substituent's 3p (or higher) orbital with the 2p orbital of the carbon. Due to a stronger resonance effect and inductive effect than the heavier halogens, fluorine is anomalous.
Download as PDF; Printable version ... magnetic resonance is a resonant effect that can appear when a magnetic dipole is exposed to a static ... the resonance ...
Contributing structures of the carbonate ion. In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, [1] also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.
However, resonance can also be detrimental, leading to excessive vibrations or even structural failure in some cases. [3] All systems, including molecular systems and particles, tend to vibrate at a natural frequency depending upon their structure; this frequency is known as a resonant frequency or resonance frequency.