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Class 3: Flammable Liquids A flammable liquid is a liquid having a flash point of not more than 60 °C (140 °F), or any material in a liquid phase with a flash point at or above 37.8 °C (100 °F) that is intentionally heated and offered for transportation or transported at or above its flash point in a bulk packaging. The following exceptions ...
A UN 4G Doublewall corrugated fiberboard box with dividers for shipping four bottles of corrosive liquid, certified to the Packing Group III performance level. The first version of the Recommendations on the Transport of Dangerous Goods was produced by the ECOSOC in 1956. [1]
Substances and mixtures which, in contact with water, emit flammable gases are categorized from 1 to 3 based on the ignitability of the gas emitted. Oxidizing liquids contribute to the combustion of other materials and are categorized from 1 to 3 in decreasing oxidizing potential. Oxidizing solids follow the same criteria as oxidizing liquids.
Flammable gases – Gases which at 20 °C and a standard pressure of 101.3 kPa: are ignitable when in a mixture of 13 percent or less by volume with air; or; have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Alternative sign. Division 2.1 Non-flammable non-toxic gases – Gases which:
Prior to bringing regulations in line with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) in 2012, OSHA considered flammable liquids to be those with a flash point below 37.8 °C/100 °F. Those with flash points above 37.8 °C/100 °F and below 93.3 °C/200 °F were classified as combustible liquids.
Includes flammable liquids with flash points below 73 °F (23 °C) and boiling points above 100 °F (38 °C), as well as liquids with flash points between 73 °F and 100 °F. 2. Materials which must be moderately heated or exposed to high ambient temperatures before ignition will occur.
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