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Building stone containing pyrite tends to stain brown as pyrite oxidizes. This problem appears to be significantly worse if any marcasite is present. [ 50 ] The presence of pyrite in the aggregate used to make concrete can lead to severe deterioration as pyrite oxidizes. [ 51 ]
Examples include pyrite nodules in coal, a chert nodule in limestone, or a phosphorite nodule in marine shale. Normally, a nodule has a warty or knobby surface and exists as a discrete mass within the host strata. In general, they lack any internal structure except for the preserved remnants of original bedding or fossils.
The strong acidification of the medium caused by pyrite oxidation releases bicarbonate ions (HCO − 3) or carbon dioxide (CO 2) along with calcium (Ca 2+) and sulfate ions (SO 2− 4). Full pyrite oxidation can be schematized as: 2 FeS 2 + 7.5 O 2 + 4 H 2 O → Fe 2 O 3 + 4 H 2 SO 4. The sulfuric acid released by pyrite oxidation then reacts ...
A new method of cleaning stone on ancient buildings (medieval and renaissance) has been developed in Europe: sulfur-reducing bacteria are used on the black gypsum-containing crusts that form on such buildings to convert the sulfur to a gas that dissipates, thus destroying the crust while leaving the patina produced by aging on the underlying stone.
Marcasite reacts more readily than pyrite under conditions of high humidity. The product of this disintegration is iron(II) sulfate and sulfuric acid. The hydrous iron sulfate forms a white powder consisting of the mineral melanterite, FeSO 4 ·7H 2 O. [13] This disintegration of marcasite in mineral collections is known as "pyrite decay".
Follow these expert-approved steps on how to clean a pizza stone. Plus, learn the best way to remove tough stains and any burnt areas with baking soda.
Tree remains that have undergone petrifaction, as seen in Petrified Forest National Park. In geology, petrifaction or petrification (from Ancient Greek πέτρα (pétra) 'rock, stone') is the process by which organic material becomes a fossil through the replacement of the original material and the filling of the original pore spaces with minerals.
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