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acetyl chloride SOCl 2 acetic acid (i) Li[AlH 4], ether (ii) H 3 O + ethanol Two typical organic reactions of acetic acid Acetic acid undergoes the typical chemical reactions of a carboxylic acid. Upon treatment with a standard base, it converts to metal acetate and water. With strong bases (e.g., organolithium reagents), it can be doubly deprotonated to give LiCH 2 COOLi. Reduction of acetic ...
An acid dissociation constant is a particular example of an equilibrium constant. The dissociation of a monoprotic acid, HA, in dilute solution can be written as + + The thermodynamic equilibrium constant can be defined by [15]
In this regard, that is depending on the number of the protons they can give up, we define monoprotic, diprotic and triprotic acids. The first (e.g., acetic acid or ammonium ) have only one dissociable group, the second (e.g., carbonic acid , bicarbonate , glycine ) have two dissociable groups and the third (e.g., phosphoric acid) have three ...
Other examples of inorganic polyprotic acids include anions of sulfuric acid, phosphoric acid and hydrogen sulfide that have lost one or more protons. In organic chemistry and biochemistry, important examples include amino acids and derivatives of citric acid. Although an amphiprotic species must be amphoteric, the converse is not true.
In the case of citric acid, the overlap is extensive and solutions of citric acid are buffered over the whole range of pH 2.5 to 7.5. Calculation of the pH with a polyprotic acid requires a speciation calculation to be performed. In the case of citric acid, this entails the solution of the two equations of mass balance:
The strength of an inorganic acid is dependent on the oxidation state for the atom to which the proton may be attached. Acid strength is solvent-dependent. For example, hydrogen chloride is a strong acid in aqueous solution, but is a weak acid when dissolved in glacial acetic acid.
The acid, HA, is a proton donor which can lose a proton to become its conjugate base, A −. The base, B, is a proton acceptor which can become its conjugate acid, HB +. Most acid–base reactions are fast, so the substances in the reaction are usually in dynamic equilibrium with each other. [8]
In chemistry, protonation (or hydronation) is the adding of a proton (or hydron, or hydrogen cation), usually denoted by H +, to an atom, molecule, or ion, forming a conjugate acid. [1] (The complementary process, when a proton is removed from a Brønsted–Lowry acid, is deprotonation.) Some examples include The protonation of water by ...