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The Hertz–Knudsen equation describes the non-dissociative adsorption of a gas molecule on a surface by expressing the variation of the number of molecules impacting on the surfaces per unit of time as a function of the pressure of the gas and other parameters which characterise both the gas phase molecule and the surface: [1] [2]
The Langmuir adsorption model deviates significantly in many cases, primarily because it fails to account for the surface roughness of the adsorbent. Rough inhomogeneous surfaces have multiple site types available for adsorption, with some parameters varying from site to site, such as the heat of adsorption.
The langmuir (symbol: L) is a unit of exposure (or dosage) to a surface (e.g. of a crystal) and is used in ultra-high vacuum (UHV) surface physics to study the adsorption of gases. It is a practical unit, and is not dimensionally homogeneous , and so is used only in this field.
English: Citations are the backbone of Wikipedia, and of most Wikipedia-based classroom assignments. This is a practical and advice-driven guide on identifying good sources, and how to cite those sources using Wiki markup. The handout introduces the citation toolbar and other areas to check for help.
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Named after Clement D. Child; also known as the Child–Langmuir law (after Irving Langmuir). See also Mott–Gurney law. Chladni's law relates the frequency of modes of vibration for flat circular surfaces with fixed center as a function of the numbers of diametric (linear) nodes and of radial (circular) nodes. Named after Ernst Chladni.
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