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The sulfoxide in sulfur chemistry is represented in selenium chemistry by the selenoxides (formula RSe(O)R), which are intermediates in organic synthesis, as illustrated by the selenoxide elimination reaction. Consistent with trends indicated by the double bond rule, selenoketones, R(C=Se)R, and selenaldehydes, R(C=Se)H, are rarely observed.
The sulfoxide in sulfur chemistry is represented in selenium chemistry by the selenoxides (formula RSe(O)R), which are intermediates in organic synthesis, as illustrated by the selenoxide elimination reaction. Consistent with trends indicated by the double bond rule, selenoketones, R(C=Se)R, and selenaldehydes, R(C=Se)H, are rarely observed.
Selenium is a component of the amino acids selenocysteine and selenomethionine. In humans, selenium is a trace element nutrient that functions as cofactor for glutathione peroxidases and certain forms of thioredoxin reductase. [1] Selenium-containing proteins are produced from inorganic selenium via the intermediacy of selenophosphate (PSeO 3 3 ...
Description: A classic general textbook for an undergraduate course in inorganic chemistry Importance: This book is not only a good introduction to the subject, it was very different from earlier texts and "led to a fundamental shift in the way in which inorganic chemistry was studied". [16]
The isotope selenium-75 has radiopharmaceutical uses. For example, it is used in high-dose-rate endorectal brachytherapy, as an alternative to iridium-192. [8]In paleobiogeochemistry, the ratio in amount of selenium-82 to selenium-76 (i.e, the value of δ 82/76 Se) can be used to track down the redox conditions on Earth during the Neoproterozoic era in order to gain a deeper understanding of ...
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In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. [1] A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction. The detailed steps of a reaction are not observable in most cases.
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