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Pb 2 (OH) 2 (NO 3) 2 is the predominant species formed at low pH. At higher pH Pb 6 (OH) 5 (NO 3) is formed. [17] The cation [Pb 6 O(OH) 6] 4+ is unusual in having an oxide ion inside a cluster of 3 face-sharing PbO 4 tetrahedra. [18] There is no evidence for the formation of the hydroxide, Pb(OH) 2, in aqueous solution below pH 12.
2 Pb(NO 3) 2 → 2 PbO + 4 NO 2 + O 2 PbCO 3 → PbO + CO 2. PbO is produced on a large scale as an intermediate product in refining raw lead ores into metallic lead. The usual lead ore is galena (lead(II) sulfide). At a temperature of around 1,000 °C (1,800 °F) the sulfide is converted to the oxide: [5] 2 PbS + 3 O 2 → 2 PbO + 2 SO 2
It dissolves in nitric acid with the evolution of nitric oxide gas to form dissolved Pb(NO 3) 2. 3 Pb + 8 H + + 8 NO − 3 → 3 Pb 2+ + 6 NO − 3 + 2 NO + 4 H 2 O. When heated with nitrates of alkali metals, metallic lead oxidizes to form PbO (also known as litharge), leaving the corresponding alkali nitrite. PbO is representative of lead's ...
Lead(II) azide is prepared by the reaction of sodium azide and lead(II) nitrate in aqueous solution. [6] [5] Lead(II) acetate can also be used.[7] [8]Thickeners such as dextrin or polyvinyl alcohol are often added to the solution to stabilize the precipitated product.
pb 3 o 4 + 4 hno 3 → pbo 2 + 2 pb(no 3) 2 + 2 h 2 o With iron oxides and with elemental iron , lead(II,IV) oxide forms insoluble iron(II) and iron(III) plumbates , which is the basis of the anticorrosive properties of lead-based paints applied to iron objects.
Lead(II) chromate can be produced by treating sodium chromate with lead salts such as lead(II) nitrate or by combining lead(II) oxide with chromic acid.. Related lead sulfochromate pigments are produced by the replacement of some chromate by sulfate, resulting in a mixed lead-chromate-sulfate compositions Pb(CrO 4) 1−x (SO 4) x.
Lead(II) thiocyanate can be formed from the acidification of lead(II) nitrate, Pb(NO 3) 2, with nitric acid, HNO 3, in the presence of thiocyanic acid, HSCN.It may also be made by reacting lead(II) acetate (Pb(CH 3 COO) 2) solved in water with either potassium thiocyanate (KSCN) or ammonium thiocyanate (NH 4 SCN), thus causing a white precipitation of solid lead(II) thiocyanate according to ...
2 is commonly synthesized via a precipitation reaction between potassium iodide KI and lead(II) nitrate Pb (NO 3) 2 in water solution: Pb(NO 3) 2 + 2 KI → PbI 2 + 2 KNO 3. While the potassium nitrate KNO 3 is soluble, the lead iodide PbI 2 is nearly insoluble at room temperature, and thus precipitates out. [17]