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Native copper is an uncombined form of copper that occurs as a natural mineral. Copper is one of the few metallic elements to occur in native form, although it most commonly occurs in oxidized states and mixed with other elements. Native copper was an important ore of copper in historic times and was used by pre-historic peoples.
Commonly, copper is either formed within sedimentary rocks, or associated with igneous rocks. The world's major copper deposits are formed within the granitic porphyry copper style. Copper is enriched by processes during crystallisation of the granite and forms as chalcopyrite — a sulfide mineral, which is carried up with the granite.
A number of copper mines also contained a notable amount of silver, both in native form and naturally alloyed with the copper. Halfbreed is the term for an ore sample that contains the pure copper and pure silver in the same piece of rock; it is only found in the native copper deposits of the Upper Peninsula of Michigan. [2]
Porphyry copper deposits represent an important resource and the dominant source of copper that is mined today to satisfy global demand. [6] Via compilation of geological data, it has been found that the majority of porphyry deposits are Phanerozoic in age and were emplaced at depths of approximately 1 to 6 kilometres with vertical thicknesses on average of 2 kilometres. [6]
Copper is one of the few metals that can occur in nature in a directly usable metallic form. This means that copper is a native metal. This led to very early human use in several regions, from c. 8000 BC.
Following is a list of minerals that serve as copper ores in the copper mining process: [1] Image Name Formula % Copper when pure Chalcopyrite: CuFeS 2: 34.5 Chalcocite:
The spectrum of copper minerals closely resembles that of silver, ranging from oxides of its multiple oxidation states through sulfides and silicates to halides and chlorates, iodates, nitrates and others. Natural alloys of copper (particularly with silver; the two metals can also be found in separate but co-mingled masses) are also found.
Malachite is a copper carbonate hydroxide mineral, with the formula Cu 2 CO 3 (OH) 2.This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation.