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Scheme of inlet ionization. In mass spectrometry, matrix-assisted ionization (also inlet ionization) is a low fragmentation (soft) ionization technique which involves the transfer of particles of the analyte and matrix sample from atmospheric pressure (AP) to the heated inlet tube connecting the AP region to the vacuum of the mass analyzer.
A common theme among these techniques is the use of a fine (10 0 –10 −3 Torr) or high (10 −3 –10 −6 Torr) vacuum to remove air, and the use of an inert gas: preferably argon, but often nitrogen. The two most common types of air-free technique involve the use of a glovebox and a Schlenk line, although some rigorous applications use a ...
Vacuum systems usually consist of gauges, vapor jet and pumps, vapor traps and valves along with other extensional piping. A vessel that is operating under vacuum system may be any of these types such as processing tank, steam simulator, particle accelerator, or any other type of space that has an enclosed chamber to maintain the system in less than atmospheric gas pressure.
Vacuum pumps: A vacuum pump sucks air or air/steam mixtures from the chamber. Superatmospheric cycles: Achieved with a vacuum pump. It starts with a vacuum followed by a steam pulse followed by a vacuum followed by a steam pulse. The number of pulses depends on the particular autoclave and cycle chosen. Subatmospheric cycles:
One of the most used plasma-based techniques for ambient ionization is probably Direct analysis in real time (DART), since it is commercially available. DART is an atmospheric pressure ion source that operates by exposing the sample to a gas stream (typically helium or nitrogen) that contains long-lived electronically or excited neutral atoms ...
A vacuum ejector, or simply ejector, or aspirator, is a type of vacuum pump, which produces vacuum by means of the Venturi effect.. In an ejector, a working fluid (liquid or gaseous) flows through a jet nozzle into a tube that first narrows and then expands in cross-sectional area.
Matrix-free conjugate gradient method has been applied in the non-linear elasto-plastic finite element solver. [7] Solving these equations requires the calculation of the Jacobian which is costly in terms of CPU time and storage. To avoid this expense, matrix-free methods are employed.
Atmospheric pressure chemical ionization chamber cross section. Atmospheric pressure chemical ionization (APCI) is an ionization method used in mass spectrometry which utilizes gas-phase ion-molecule reactions at atmospheric pressure (10 5 Pa), [1] [2] commonly coupled with high-performance liquid chromatography (HPLC). [3]