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[a] While processes in isolated systems are never reversible, [3] cyclical processes can be reversible or irreversible. [4] Reversible processes are hypothetical or idealized but central to the second law of thermodynamics. [3] Melting or freezing of ice in water is an example of a realistic process that is nearly reversible.
where a reversible path is chosen from absolute zero to the final state, so that for an isothermal reversible process Δ S = Q r e v T {\displaystyle \Delta S={Q_{rev} \over T}} . In general, for any cyclic process the state points can be connected by reversible paths, so that
Endoreversible thermodynamics is a subset of irreversible thermodynamics aimed at making more realistic assumptions about heat transfer than are typically made in reversible thermodynamics. It gives an upper bound on the power that can be derived from a real process that is lower than that predicted by Carnot for a Carnot cycle , and ...
In some cases, when analyzing a thermodynamic process, one can assume that each intermediate state in the process is at equilibrium. Such a process is called quasistatic. [4] For a process to be reversible, each step in the process must be reversible. For a step in a process to be reversible, the system must be in equilibrium throughout the step.
Another cycle that features isothermal heat-addition and heat-rejection processes is the Stirling cycle, which is an altered version of the Carnot cycle in which the two isentropic processes featured in the Carnot cycle are replaced by two constant-volume regeneration processes. The cycle is reversible, meaning that if supplied with mechanical ...
A process is said to be physically reversible if it results in no increase in physical entropy; it is isentropic. There is a style of circuit design ideally exhibiting this property that is referred to as charge recovery logic , adiabatic circuits , or adiabatic computing (see Adiabatic process ).
Many redox processes observed by CV are quasi-reversible or non-reversible. In such cases the thermodynamic potential E 0 1/2 is often deduced by simulation. The irreversibility is indicated by i pa /i pc ≠ 1. Deviations from unity are attributable to a subsequent chemical reaction that is triggered by the electron transfer.
For a particular reversible process in general, the work done reversibly on the system, ,, and the heat transferred reversibly to the system, , are not required to occur respectively adiabatically or adynamically, but they must belong to the same particular process defined by its particular reversible path, , through the space of thermodynamic ...
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