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A close packed unit cell, both face-centered cubic and hexagonal close packed, can form two different shaped holes. Looking at the three green spheres in the hexagonal packing illustration at the top of the page, they form a triangle-shaped hole. If an atom is arranged on top of this triangular hole it forms a tetrahedral interstitial hole.
[4] [5] The bcc and fcc, with their higher densities, are both quite common in nature. Examples of bcc include iron, chromium, tungsten, and niobium. Examples of fcc include aluminium, copper, gold and silver. Another important cubic crystal structure is the diamond cubic structure, which can appear in carbon, silicon, germanium, and tin.
In both of these very similar lattices there are two sorts of interstice, or hole: Two tetrahedral holes per metal atom, i.e. the hole is between four metal atoms; One octahedral hole per metal atom, i.e. the hole is between six metal atoms; It was suggested by early workers that: the metal lattice was relatively unaffected by the interstitial atom
Two octahedral layers usually allow for four structural arrangements that can either be filled by an hpc of fcc packing systems. In filling tetrahedral holes a complete filling leads to fcc field array. In unit cells, hole filling can sometimes lead to polyhedral arrays with a mix of hcp and fcc layering. [10]
When it dissolves in iron, carbon atoms occupy interstitial "holes". Being about twice the diameter of the tetrahedral hole, the carbon introduces a strong local strain field. Mild steel (carbon steel with up to about 0.2 wt% C) consists mostly of α-Fe and increasing amounts of cementite (Fe 3 C, an iron carbide).
The fluorite structure refers to a common motif for compounds with the formula MX 2. [1] [2] The X ions occupy the eight tetrahedral interstitial sites whereas M ions occupy the regular sites of a face-centered cubic (FCC) structure.
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In condensed matter physics and inorganic chemistry, the cation-anion radius ratio can be used to predict the crystal structure of an ionic compound based on the relative size of its atoms.