Search results
Results from the WOW.Com Content Network
By the equipartition theorem, internal energy per mole of gas equals c v T, where T is absolute temperature and the specific heat at constant volume is c v = (f)(R/2). R = 8.314 J/(K mol) is the universal gas constant, and "f" is the number of thermodynamic (quadratic) degrees of freedom, counting the number of ways in which energy can occur.
Normal coordinates decouple the classical vibrational motions of the molecule and thus give an easy route to obtaining vibrational amplitudes of the atoms as a function of time. In Wilson's GF method it is assumed that the molecular kinetic energy consists only of harmonic vibrations of the atoms, i.e., overall rotational and translational ...
The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules. The energy spectrum of a system with such discrete energy levels is said to be quantized.
The terms kinetic energy and work in their present scientific meanings date back to the mid-19th century. Early understandings of these ideas can be attributed to Thomas Young, who in his 1802 lecture to the Royal Society, was the first to use the term energy to refer to kinetic energy in its modern sense, instead of vis viva.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
For example, for the bond of an electrical system, the flow is the current, while the effort is the voltage. By multiplying current and voltage in this example you can get the instantaneous power of the bond. A bond has two other features described briefly here, and discussed in more detail below. One is the "half-arrow" sign convention.
A physical constant relating the average kinetic energy of the particles in a gas with the temperature of the gas. It is the gas constant R divided by the Avogadro constant NA. Bose–Einstein condensate (BEC) boson A type of subatomic particle that behaves according to Bose–Einstein statistics and possesses integer spin.
As a collection of classical material particles, the temperature is a measure of the mean energy of motion, called translational kinetic energy, of the particles, whether in solids, liquids, gases, or plasmas. The kinetic energy, a concept of classical mechanics, is half the mass of a particle times its speed squared. In this mechanical ...