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This equation, Bragg's law, describes the condition on θ for constructive interference. [12] A map of the intensities of the scattered waves as a function of their angle is called a diffraction pattern. Strong intensities known as Bragg peaks are obtained in the diffraction pattern when the scattering angles satisfy Bragg condition.
The example of scattering in quantum chemistry is particularly instructive, as the theory is reasonably complex while still having a good foundation on which to build an intuitive understanding. When two atoms are scattered off one another, one can understand them as being the bound state solutions of some differential equation.
In X-ray crystallography, wide-angle X-ray scattering (WAXS) or wide-angle X-ray diffraction (WAXD) is the analysis of Bragg peaks scattered to wide angles, which (by Bragg's law) are caused by sub-nanometer-sized structures. [1] It is an X-ray-diffraction [2] method and commonly used to determine a range of information about crystalline materials.
The momentum transfer plays an important role in the evaluation of neutron, X-ray, and electron diffraction for the investigation of condensed matter. Laue-Bragg diffraction occurs on the atomic crystal lattice, conserves the wave energy and thus is called elastic scattering, where the wave numbers final and incident particles, and , respectively, are equal and just the direction changes by a ...
While the Bragg formulation assumes a unique choice of direct lattice planes and specular reflection of the incident X-rays, the Von Laue formula only assumes monochromatic light and that each scattering center acts as a source of secondary wavelets as described by the Huygens principle. Each scattered wave contributes to a new plane wave given by:
where G, R g, and B are constants related to the scattering contrast, structural volume, surface area, and radius of gyration. q is the magnitude of the scattering vector which is related to the Bragg spacing, d, q = 2π/d = 4π/λ sin(θ/2). λ is the wavelength and θ is the scattering angle (2θ in diffraction).
As opposed to crystallographic scattering experiments, where the scatterer or "target" has very distinct order, which leads to well defined patterns (presenting Bragg peaks for example), the stochastic nature of polymer configurations and deformations (especially in a solution), gives rise to quite different results.
where the magnitude of the scattering vector q is in reciprocal lattice distance units, N is the number of atoms, f i (q) is the atomic scattering factor for atom i and scattering vector q, while r ij is the distance between atom i and atom j. One can also use this to predict the effect of nano-crystallite shape on detected diffraction peaks ...