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The higher the saponification value, the lower the fatty acids average length, the lighter the mean molecular weight of triglycerides and vice versa. Practically, fats or oils with high saponification value (such as coconut and palm oil) are more suitable for soap making.
Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. [1] [2] It is an important type of alkaline hydrolysis. When the carboxylate is long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate ...
Iodine value helps to classify oils according to the degree of unsaturation into drying oils, having IV > 150 (i.e. linseed, tung), semi-drying oils IV : 125 – 150 ( soybean, sunflower) and non-drying oils with IV < 125 (canola, olive, coconut). The IV ranges of several common oils and fats is provided by the table below.
Beeswax is an ingredient in surgical bone wax, which is used during surgery to control bleeding from bone surfaces; shoe polish and furniture polish can both use beeswax as a component, dissolved in turpentine or sometimes blended with linseed oil or tung oil; modeling waxes can also use beeswax as a component; pure beeswax can also be used as ...
Sodium methoxide is prepared by treating methanol with sodium: 2 Na + 2 CH 3 OH → 2 CH 3 ONa + H 2. The reaction is so exothermic that ignition is possible. The resulting solution, which is colorless, is often used as a source of sodium methoxide, but the pure material can be isolated by evaporation followed by heating to remove residual methanol.
The conversion between hydroxyl value and other hydroxyl content measurements is obtained by multiplying the hydroxyl value by the factor 17/560. [2] The chemical substance may be a fat, oil, natural or synthetic ester, or other polyol. [3] ASTM D 1957 [4] and ASTM E222-10 [5] describe several versions of this method of determining hydroxyl value.
The Reichert value is an indicator of how much volatile fatty acid can be extracted from a particular fat or oil through saponification. It is equal to the number of millilitres of 0.1 normal hydroxide solution necessary for the neutralization of the water-soluble volatile fatty acids distilled and filtered from 5 grams of a given saponified fat.
CH 3 (CH 2) 20 COOH C22:0 Tricosylic acid: Tricosanoic acid CH 3 (CH 2) 21 COOH C23:0 Lignoceric acid: Tetracosanoic acid CH 3 (CH 2) 22 COOH C24:0 Pentacosylic acid: Pentacosanoic acid CH 3 (CH 2) 23 COOH C25:0 Cerotic acid: Hexacosanoic acid CH 3 (CH 2) 24 COOH C26:0 Carboceric acid: Heptacosanoic acid CH 3 (CH 2) 25 COOH C27:0 Montanic acid ...