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A key physical factor which distinguishes the LCST from other mixture behavior is that the LCST phase separation is driven by unfavorable entropy of mixing. [18] Since mixing of the two phases is spontaneous below the LCST and not above, the Gibbs free energy change (ΔG) for the mixing of these two phases is negative below the LCST and positive above, and the entropy change ΔS = – (dΔG/dT ...
The relationship between entropy, order, and disorder in the Boltzmann equation is so clear among physicists that according to the views of thermodynamic ecologists Sven Jorgensen and Yuri Svirezhev, "it is obvious that entropy is a measure of order or, most likely, disorder in the system."
In certain blends, mixing entropy can dominate over monomer interaction. By adopting the mean-field approximation, parameter complex dependence on temperature, blend composition, and chain length was discarded. Specifically, interactions beyond the nearest neighbor may be highly relevant to the behavior of the blend and the distribution of ...
As a result, the entropy decreases in the system, ΔS p < 0 for nearly all polymerization processes. Since depolymerization is almost always entropically favored, the ΔH p must then be sufficiently negative to compensate for the unfavorable entropic term. Only then will polymerization be thermodynamically favored by the resulting negative ΔG p.
Although entropy does increase in the model of an expanding universe, the maximum possible entropy rises much more rapidly, moving the universe further from the heat death with time, not closer. [ 96 ] [ 97 ] [ 98 ] This results in an "entropy gap" pushing the system further away from the posited heat death equilibrium. [ 99 ]
Depolymerization is a very common process. Digestion of food involves depolymerization of macromolecules, such as proteins.It is relevant to polymer recycling.Sometimes the depolymerization is well behaved, and clean monomers can be reclaimed and reused for making new plastic.
The definition of entropy is central to the establishment of the second law of thermodynamics, which states that the entropy of isolated systems cannot decrease with time, as they always tend to arrive at a state of thermodynamic equilibrium, where the entropy is highest. Entropy is therefore also considered to be a measure of disorder in the ...
The entropy of the surrounding room decreases less than the entropy of the ice and water increases: the room temperature of 298 K is larger than 273 K and therefore the ratio, (entropy change), of δQ / 298 K for the surroundings is smaller than the ratio (entropy change), of δQ / 273 K for the ice and water system. This is ...