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Dissimilar metals and alloys have different electrode potentials, and when two or more come into contact in an electrolyte, one metal (that is more reactive) acts as anode and the other (that is less reactive) as cathode. The electropotential difference between the reactions at the two electrodes is the driving force for an accelerated attack ...
The galvanic series (or electropotential series) determines the nobility of metals and semi-metals. When two metals are submerged in an electrolyte, while also electrically connected by some external conductor, the less noble (base) will experience galvanic corrosion. The rate of corrosion is determined by the electrolyte, the difference in ...
Sheet metal forming, thread manufacturing, and other industrial operations may include moving parts, or contact surfaces made of stainless steel, aluminium, titanium, and other metals whose natural development of an external oxide layer through passivation increases their corrosion resistance but renders them particularly susceptible to galling.
Another issue is the joining of aluminum wire to copper wire. In addition to the oxidation that occurs on the surface of aluminum wires which can cause a poor connection, aluminum and copper are dissimilar metals. As a result, galvanic corrosion can occur in the presence of an electrolyte, causing these connections to become unstable over time.
Care must be taken to avoid galvanic corrosion between the braze and the base metal, and especially between dissimilar base metals being brazed together. Formation of brittle intermetallic compounds on the alloy interface can cause joint failure.
General purpose filler metal, can be used with brazeable aluminiums in all types of brazing. For joining aluminium and its alloys. Can be used for joining aluminium and titanium to dissimilar metals; the risk of galvanic corrosion then has to be considered. Excellent corrosion resistance when joining aluminiums. Grayish-white color.
Dielectric unions, with dielectric insulation, separate dissimilar metals (such as copper and galvanized steel) to prevent galvanic corrosion. When two dissimilar metals are in contact with an electrically conductive solution (ordinary tap water is conductive), they form an electrochemical couple which generates a voltage by electrolysis.
Corrosion engineering is an engineering specialty that applies scientific, technical, engineering skills, and knowledge of natural laws and physical resources to design and implement materials, structures, devices, systems, and procedures to manage corrosion. [1]