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In methyl thiocyanate, N≡C and C−S distances are 116 and 176 pm. By contrast, N=C and C=S distances are 117 and 158 pm in isothiocyanates. [7] Typical bond angles for C−S−C are 100°. [3] By contrast C−N=C in aryl isothiocyanates is 165°. Again, the thiocyanate isomers are quite different with C−S−C angle near 100°.
Thiocyanate [6] is known to be an important part in the biosynthesis of hypothiocyanite by a lactoperoxidase. [7] [8] [9] Thus the complete absence of thiocyanate or reduced thiocyanate [10] in the human body, (e.g., cystic fibrosis) is damaging to the human host defense system.
Allyl thiocyanate isomerizes to the isothiocyanate: [4] CH 2 =CHCH 2 SCN → CH 2 =CHCH 2 NCS. Isothiocyanates can be prepared by treating organic dithiocarbamate salts with lead nitrate or tosyl chloride. [5] [6] Synthesis of phenyl isothiocyanate. Isothiocyanates may also be accessed by the fragmentation reactions of 1,4,2-oxathiazoles. [7]
3.486 951 955 119 47 × 10 21: C 51 H 104: n-henpentacontane: 52 8 031 081 780 535 296 591: 1.092 126 741 043 54 × 10 22: C 52 H 106: n-dopentacontane: 53 2.155 777 191 357 26 × 10 19: 3.423 721 299 907 32 × 10 22: C 53 H 108: n-tripentacontane: 54 5.791 918 087 314 84 × 10 19: 1.074 254 564 589 75 × 10 23: C 54 H 110: n-tetrapentacontane ...
Download as PDF; Printable version; ... This list may not reflect recent changes. Organic thiocyanates; Thiocyanate;
The Hg(SCN) 3− ion can also exist independently and is easily generated from the compounds above, amongst others. [5] Organic halides attack Hg(SCN) 2 to give a mercuric halide and a mixture of the corresponding thiocyanate and isothiocyanate. [6] Mercuric thiocyanate catalyzes HSCN or BrSCN addition (either reagent formed in situ) to alkynes ...
Sodium thiocyanate (sometimes called sodium sulphocyanide) is the chemical compound with the formula NaSCN. This colorless deliquescent salt is one of the main sources of the thiocyanate anion . As such, it is used as a precursor for the synthesis of pharmaceuticals and other specialty chemicals . [ 2 ]
[citation needed] The main method involves the thermal rearrangement of methyl thiocyanate: [1] CH 3 S−C≡N → CH 3 N=C=S. It is also prepared via with the reaction of methylamine with carbon disulfide followed by oxidation of the resulting dithiocarbamate with hydrogen peroxide. A related method is useful to prepare this compound in the ...