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Manganese(II) oxide is an inorganic compound with chemical formula MnO. [2] It forms green crystals. The compound is produced on a large scale as a component of fertilizers and food additives .
Manganese oxide is any of a variety of manganese oxides and hydroxides. [1] These include Manganese(II) oxide, MnO; Manganese(II,III) oxide, Mn 3 O 4; Manganese(III) oxide, Mn 2 O 3; Manganese dioxide, MnO 2; Manganese(VI) oxide, MnO 3; Manganese(VII) oxide, Mn 2 O 7; Other manganese oxides include Mn 5 O 8, Mn 7 O 12 and Mn 7 O 13.
Manganese dioxide is the inorganic compound with the formula MnO 2 . This blackish or brown solid occurs naturally as the mineral pyrolusite , which is the main ore of manganese and a component of manganese nodules .
Manganese(IV) oxide (manganese dioxide, MnO 2) is used as a reagent in organic chemistry for the oxidation of benzylic alcohols (where the hydroxyl group is adjacent to an aromatic ring). Manganese dioxide has been used since antiquity to oxidize and neutralize the greenish tinge in glass from trace amounts of iron contamination. [45]
Manganese(II,III) oxide is the chemical compound with formula Mn 3 O 4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO · Mn 2 O 3 . Mn 3 O 4 is found in nature as the mineral hausmannite .
Manganese(III) oxide is a chemical compound with the formula Mn 2 O 3. It occurs in nature as the mineral bixbyite (recently changed to bixbyite-(Mn) [ 3 ] [ 4 ] ) and is used in the production of ferrites and thermistors .
A permanganate (/ p ər ˈ m æ ŋ ɡ ə n eɪ t, p ɜːr-/) [1] is a chemical compound with the manganate(VII) ion, MnO − 4, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent. The ion is a transition metal ion with a tetrahedral structure. [2]
Manganese(II) hydroxide precipitates as a solid when an alkali metal hydroxide is added to an aqueous solution of Mn 2+ salt: [3] Mn 2+ + 2 NaOH → Mn(OH) 2 + 2 Na + Manganese(II) hydroxide oxidises readily in air, as indicated by darkening of samples. The compound adopts the brucite structure, as do several other metal dihydroxides.