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Hydrogen telluride is the inorganic compound with the formula H 2 Te.A hydrogen chalcogenide and the simplest hydride of tellurium, it is a colorless gas.Although unstable in ambient air, the gas can exist long enough to be readily detected by the odour of rotting garlic at extremely low concentrations; or by the revolting odour of rotting leeks at somewhat higher concentrations.
The telluride ion is the anion Te 2− and its derivatives. It is analogous to the other chalcogenide anions, the lighter O 2−, S 2−, and Se 2−, and the heavier Po 2−. [1] In principle, Te 2− is formed by the two-e − reduction of tellurium. The redox potential is −1.14 V. [2] Te(s) + 2 e − ↔ Te 2−
This salt is the conjugate base of the thermally unstable acid hydrogen telluride, but it is usually prepared by reduction of tellurium with sodium. Na 2 Te is a challenging material to handle because it is very sensitive to air. Air oxidizes it initially to polytellurides, which have the formula Na 2 Te x (x > 1), and ultimately Te metal.
Tellurous acid is an inorganic compound with the formula H 2 TeO 3. It is the oxoacid of tellurium(IV). [2] This compound is not well characterized. An alternative way of writing its formula is (HO) 2 TeO. In principle, tellurous acid would form by treatment of tellurium dioxide with water, that is by hydrolysis.
Telluric acid, or more accurately orthotelluric acid, is a chemical compound with the formula Te(OH) 6, often written as H 6 TeO 6. It is a white crystalline solid made up of octahedral Te(OH) 6 molecules which persist in aqueous solution. [ 3 ]
Structure of tellurium tetrachloride, tetrabromide and tetraiodide. The +2 oxidation state is exhibited by the dihalides, TeCl 2, TeBr 2 and TeI 2.The dihalides have not been obtained in pure form, [3]: 274 although they are known decomposition products of the tetrahalides in organic solvents, and the derived tetrahalotellurates are well-characterized:
Compounds that contain the anions follow basic nomenclature rules, the cation is named first, followed by the anion. [2] As individual ions current IUPAC naming conventions dictate that compounds containing what was conventionally known as the tellurite ion, [TeO 3 ] 2- , be named as tellurate (IV) compounds, while other tellurates are labeled ...
Crystal structure of sodium tellurite, highlighting the pyramidal structure of the anion. Tellurite dianion is pyramidal, like selenite and sulfite. The anion has C 3v symmetry. Tellurites can be reduced to elemental tellurium by electrolysis or a strong reducing agent. When fused with nitrate salts, tellurite salts oxidize to tellurates (TeO 2 ...