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Stan Lee is responsible with helping create the most villains for the web-slinger and helped pave the way for the fictional rogues gallery. The majority of supervillains depicted in Spider-Man comics first appeared in The Amazing Spider-Man, while some first appeared in spinoff comics such as The Spectacular Spider-Man and Marvel Team-Up and other titles.
A few of Spider-Man villains in other media have joined the group Sinister Six (or Insidious Six in Spider-Man: The Animated Series and Sinister Seven or Superior Sinister Six in Ultimate Spider-Man) to take down Spider-Man just like in the comics. Here is a list of villains who have joined.
The members of the original Sinister Six. The Sinister Six are a group of supervillains in the Marvel Comics universe, drawn from Spider-Man's rogues gallery.There are several different formations of the group along the history of Marvel Comics' publications whose objectives vary from joining forces against Spider-Man or another common enemy to world domination mostly facing spider-man.
A. Abraxas (comics) Absalom (comics) Absorbing Man; Achilles (Pantheon) Acrobat (comics) Adam II; Adria (comics) Aggamon; Aguja (Marvel Comics) List of incarnations of Spider-Man
This category collects images that are scans, screen captures, photos, and/or illustrations of Spider-Man and related characters and intellectual properties for which Marvel Comics holds the copyright and/or trademark.
The Amazing Spider-Man #340 (Oct. 1990) Elizabeth Rawson is the original leader of the Femme Fatales, and has superhuman strength and endurance. Cybernetic parts of her costume suggest that her already advanced strength is augmented when needed and also provides body armor. Mindblast: The Amazing Spider-Man #340 (Oct. 1990)
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S. Sandman (Marvel Comics) Scorcher (character) Scream (character) Screwball (character) Shocker (character) Shriek (character) Silk (character) Silver Sable