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In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Svante August Arrhenius (/ ə ˈ r iː n i ə s, ə ˈ r eɪ n i ə s / ə-REE-nee-əs, - RAY-, [3] [4] Swedish: [ˈsvânːtɛ aˈrěːnɪɵs]; 19 February 1859 – 2 October 1927) was a Swedish scientist. Originally a physicist, but often referred to as a chemist, Arrhenius was one of the founders of the science of physical chemistry.
Arrhenius definition, Svante Arrhenius definition of acids and bases; Arrhenius equation, Svante Arrhenius formula for modeling the temperature dependence of reaction ...
Svante Arrhenius. The first modern definition of acids and bases in molecular terms was devised by Svante Arrhenius. [9] [10] A hydrogen theory of acids, it followed from his 1884 work with Friedrich Wilhelm Ostwald in establishing the presence of ions in aqueous solution and led to Arrhenius receiving the Nobel Prize in Chemistry in 1903.
However, the Arrhenius equation was derived from experimental data and models the macroscopic rate using only two parameters, irrespective of the number of transition states in a mechanism. In contrast, activation parameters can be found for every transition state of a multistep mechanism, at least in principle.
In 1884, Svante Arrhenius proposed that a base is a substance which dissociates in aqueous solution to form hydroxide ions OH −. These ions can react with hydrogen ions (H + according to Arrhenius) from the dissociation of acids to form water in an acid–base reaction. A base was therefore a metal hydroxide such as NaOH or Ca(OH) 2.
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Accelerated aging techniques, particularly those using the Arrhenius equation, have frequently been criticized in recent decades. While some researchers claim that the Arrhenius equation can be used to quantitatively predict the lifespan of tested papers, [9] other researchers disagree. Many argue that this method cannot predict an exact ...