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Purification is challenging because the individual isomers have similar properties. The 2,6 and 3,5 isomers do not form acceptably from toluene or chlorotoluenes, so these isomers are prepared by indirect methods. For example, 2,6-dichlorotoluene can be prepared by chlorination of 4-toluenesulfonyl chloride followed by desulfonation. [1]
A laboratory route to 2- and 4-chlorotoluene proceeds from 2- and 4-toluidines (i.e. 2- and 4-aminotoluene). These compounds are diazotized followed by treatment with cuprous chloride. [1] Industrially, the diazonium method is reserved for 3-chlorotoluene. The industrial route to 2- and 4-chlorotoluene entails direct reaction of toluene with ...
2,4-Dichlorobenzoic acid is an organic compound with the formula C 6 H 3 Cl 2 CO 2 H. It is one of more important of several isomers of dichlorobenzoic acid. It can be prepared by oxidation of 2,4-dichlorotoluene. [2] The coenzyme A thioester of 2,4-dichlorobenzoic acid is the substrate for 2,4-dichlorobenzoyl reductase.
The derived quantity relative molecular mass is the unitless ratio of the mass of a molecule to the atomic mass constant (which is equal to one dalton). [2] The molecular mass and relative molecular mass are distinct from but related to the molar mass. The molar mass is defined as the mass of a given substance divided by the amount of the ...
Thermodynamic datafile for MgCl 2 (c,l,g) from FREED. Some values have truncated significant figures for display purposes. The explanation for the values is shown below. Row 1. Molar mass of species, density at 298.15 K, ΔH° form 298.15, S° 298.15. and the upper temperature limit for the file. Row 2. Number of C p equations required. Here ...
Energy density per unit mass J⋅kg −1: L 2 T −2: intensive Specific heat capacity: c: Heat capacity per unit mass J/(K⋅kg) L 2 T −2 Θ −1: intensive Specific volume: v: Volume per unit mass (reciprocal of density) m 3 ⋅kg −1: L 3 M −1: intensive Spin: S: Quantum-mechanically defined angular momentum of a particle kg⋅m 2 ⋅s ...
2,4-Dichlorophenol (2,4-DCP) is a chlorinated derivative of phenol with the molecular formula Cl 2 C 6 H 3 OH. It is a white solid that is mildly acidic (pK a = 7.9). It is produced on a large scale as a precursor to the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D).
Standard molar entropy S o solid? J/(mol K) Heat capacity c p liquid: 181,2 J/(mol K) Heat capacity c p gas: 103,6 J/(mol K) Liquid properties Std enthalpy change of formation Δ f H o liquid +12.0 kJ/mol Standard molar entropy S o liquid: 220.96 J/(mol K) Heat capacity c p: 155.96 J/(mol K) Gas properties Std enthalpy change of formation Δ f ...