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Thermal equilibrium is achieved when two systems in thermal contact with each other cease to have a net exchange of energy. It follows that if two systems are in thermal equilibrium, then their temperatures are the same. [64] Thermal equilibrium occurs when a system's macroscopic thermal observables have ceased to change with time.
Le Châtelier's principle (1884) predicts the behavior of an equilibrium system when changes to its reaction conditions occur. If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to partially reverse the change. For example, adding more S (to the chemical reaction above) from the outside will ...
Donnan equilibrium, the distribution of ion species between two ionic solutions separated by a semipermeable membrane or boundary; Dynamic equilibrium, the state in which two reversible processes occur at the same rate; Equilibrium constant, a quantity characterizing a chemical equilibrium in a chemical reaction
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
A central aim in equilibrium thermodynamics is: given a system in a well-defined initial state of thermodynamic equilibrium, subject to accurately specified constraints, to calculate, when the constraints are changed by an externally imposed intervention, what the state of the system will be once it has reached a new equilibrium. An equilibrium ...
For a reversible reaction, the equilibrium constant can be measured at a variety of temperatures. This data can be plotted on a graph with ln K eq on the y -axis and 1 / T on the x axis. The data should have a linear relationship, the equation for which can be found by fitting the data using the linear form of the Van 't Hoff equation
At equilibrium, the rate of transfer of CO 2 from the gas to the liquid phase is equal to the rate from liquid to gas. In this case, the equilibrium concentration of CO 2 in the liquid is given by Henry's law , which states that the solubility of a gas in a liquid is directly proportional to the partial pressure of that gas above the liquid. [ 1 ]
If two systems are both in thermal equilibrium with a third system, then they are in thermal equilibrium with each other. [4] Though this version of the law is one of the most commonly stated versions, it is only one of a diversity of statements that are labeled as "the zeroth law".