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Sodium hydride is the chemical compound with the empirical formula Na H.This alkali metal hydride is primarily used as a strong yet combustible base in organic synthesis.NaH is a saline (salt-like) hydride, composed of Na + and H − ions, in contrast to molecular hydrides such as borane, silane, germane, ammonia, and methane.
The hydride adds to an electrophilic center, typically unsaturated carbon. Hydrides such as sodium hydride and potassium hydride are used as strong bases in organic synthesis. The hydride reacts with the weak Bronsted acid releasing H 2. Hydrides such as calcium hydride are used as desiccants, i.e. drying agents, to remove trace water from ...
The following reaction represents the general reaction between a base (B) and water to produce a conjugate acid (BH +) and a conjugate base (OH −): [3] + + + The equilibrium constant, K b, for this reaction can be found using the following general equation: [3]
Binary hydrogen compounds in group 1 are the ionic hydrides (also called saline hydrides) wherein hydrogen is bound electrostatically. Because hydrogen is located somewhat centrally in an electronegative sense, it is necessary for the counterion to be exceptionally electropositive for the hydride to possibly be accurately described as truly behaving ionic.
In organic chemistry, a hydrate is a compound formed by the hydration, i.e. "Addition of water or of the elements of water (i.e. H and OH) to a molecular entity". [5] For example: ethanol , CH 3 −CH 2 −OH , is the product of the hydration reaction of ethene , CH 2 =CH 2 , formed by the addition of H to one C and OH to the other C, and so ...
Sodium aluminium hydride is a strong reducing agent, very similar in reactivity to lithium aluminium hydride (LAH) and, to some extent, Diisobutylaluminium hydride (DIBAL) in organic reactions. [6] It is much more powerful reducing agent than sodium borohydride due to the weaker and more polar Al-H bond compared to the
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KH reacts with water according to the reaction: KH + H 2 O → KOH + H 2. As a superbase, potassium hydride is more basic than sodium hydride. It is used to deprotonate certain carbonyl compounds to give enolates. It also deprotonates amines to give the corresponding amides of the type KNHR and KNR 2. [6]