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Sodium hydride is the chemical compound with the empirical formula Na H.This alkali metal hydride is primarily used as a strong yet combustible base in organic synthesis.NaH is a saline (salt-like) hydride, composed of Na + and H − ions, in contrast to molecular hydrides such as borane, silane, germane, ammonia, and methane.
The hydride adds to an electrophilic center, typically unsaturated carbon. Hydrides such as sodium hydride and potassium hydride are used as strong bases in organic synthesis. The hydride reacts with the weak Bronsted acid releasing H 2. Hydrides such as calcium hydride are used as desiccants, i.e. drying agents, to remove trace water from ...
Group 1: Alkali metals Reaction of sodium (Na) and water Reaction of potassium (K) in water. The alkali metals (Li, Na, K, Rb, Cs, and Fr) are the most reactive metals in the periodic table - they all react vigorously or even explosively with cold water, resulting in the displacement of hydrogen.
Metal hydrides (sodium hydride, lithium aluminium hydride, uranium trihydride) Partially or fully alkylated derivatives of metal and nonmetal hydrides (diethylaluminium hydride, trimethylaluminium, triethylaluminium, butyllithium), with a few exceptions (i.e. dimethylmercury and tetraethyllead) Copper fuel cell catalysts (zinc oxide, aluminium ...
Sodium borohydride is an odorless white to gray-white microcrystalline powder that often forms lumps. It can be purified by recrystallization from warm (50 °C) diglyme. [10] Sodium borohydride is soluble in protic solvents such as water and lower alcohols. It also reacts with these protic solvents to produce H 2; however, these reactions are ...
KH reacts with water according to the reaction: KH + H 2 O → KOH + H 2. As a superbase, potassium hydride is more basic than sodium hydride. It is used to deprotonate certain carbonyl compounds to give enolates. It also deprotonates amines to give the corresponding amides of the type KNHR and KNR 2. [6]
Sodium amide is a common reagent with a long history of laboratory use. [9] It can decompose violently on contact with water, producing ammonia and sodium hydroxide: NaNH 2 + H 2 O → NH 3 + NaOH. When burned in oxygen, it will give oxides of sodium (which react with the produced water, giving sodium hydroxide) along with nitrogen oxides:
Sodium aluminium hydride is a strong reducing agent, very similar in reactivity to lithium aluminium hydride (LAH) and, to some extent, Diisobutylaluminium hydride (DIBAL) in organic reactions. [6] It is much more powerful reducing agent than sodium borohydride due to the weaker and more polar Al-H bond compared to the B-H bond.