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The Haber process, [1] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [ 2 ] [ 3 ] It converts atmospheric nitrogen (N 2 ) to ammonia (NH 3 ) by a reaction with hydrogen (H 2 ) using finely divided iron metal as a catalyst:
Born–Haber cycles are used primarily as a means of calculating lattice energy (or more precisely enthalpy [note 1]), which cannot otherwise be measured directly. The lattice enthalpy is the enthalpy change involved in the formation of an ionic compound from gaseous ions (an exothermic process ), or sometimes defined as the energy to break the ...
The dominant technology for abiological nitrogen fixation is the Haber process, which uses iron-based heterogeneous catalysts and H 2 to convert N 2 to NH 3. This article focuses on homogeneous (soluble) catalysts for the same or similar conversions.
The Haber process, [146] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [147] [148] It converts atmospheric nitrogen (N 2) to ammonia (NH 3) by a reaction with hydrogen (H 2) using finely divided iron metal as a catalyst:
As a result, high pressures are needed to drive the reaction forward. The German chemists Fritz Haber and Carl Bosch developed the process in the first decade of the 20th century, and its improved efficiency over existing methods such as the Birkeland-Eyde and Frank-Caro processes was a major advancement in the industrial production of ammonia.
The dominant industrial method for producing ammonia is the Haber process also known as the Haber-Bosch process. [70] Fertilizer production is now the largest source of human-produced fixed nitrogen in the terrestrial ecosystem. Ammonia is a required precursor to fertilizers, explosives, and other products. The Haber process requires high ...
Haber process; Haber–Weiss reaction; Haber's rule; History of the Haber process; I. Clara Immerwahr This page was last edited on 18 June 2024, at 23:03 (UTC). Text ...
The main finding of Haber and Weiss was that hydrogen peroxide (H 2 O 2) is decomposed by a chain reaction. [2] The Haber–Weiss reaction chain proceeds by successive steps: (i) initiation, (ii) propagation and (iii) termination. The chain is initiated by the Fenton reaction: Fe 2+ + H 2 O 2 → Fe 3+ + HO – + HO • (step 1: initiation)