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Indicative of its high reactivity (relative to alkyl chlorides), benzyl chloride slowly reacts with water in a hydrolysis reaction to form benzyl alcohol and hydrochloric acid. In contact with mucous membranes, hydrolysis produces hydrochloric acid. Thus, benzyl chloride is a lachrymator and has been used in chemical warfare. It is also very ...
Schotten–Baumann reaction also refers to the conversion of acid chloride to esters. The reaction was first described in 1883 by German chemists Carl Schotten and Eugen Baumann. [1] [2] The name "Schotten–Baumann reaction conditions" often indicate the use of a two-phase solvent system, consisting of water and an organic solvent.
Benzyl alcohol is a colorless liquid with a mild pleasant aromatic odor. It is useful as a solvent for its polarity, low toxicity, and low vapor pressure. Benzyl alcohol has moderate solubility in water (4 g/100 mL) and is miscible in alcohols and diethyl ether.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
For example, a solution of table salt, also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl − (aq). The word aqueous (which comes from aqua) means pertaining to, related to, similar to, or dissolved in, water. [1] [2] As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent ...
The classic Finkelstein reaction entails the conversion of an alkyl chloride or an alkyl bromide to an alkyl iodide by treatment with a solution of sodium iodide in acetone. Sodium iodide is soluble in acetone while sodium chloride and sodium bromide are not; [ 3 ] therefore, the reaction is driven toward products by mass action due to the ...
Benzoyl chloride, also known as benzenecarbonyl chloride, is an organochlorine compound with the formula C 7 H 5 ClO. It is a colourless, fuming liquid with an irritating odour, and consists of a benzene ring ( C 6 H 6 ) with an acyl chloride ( −C(=O)Cl ) substituent .
By reaction with alcohols, benzoyl chloride can be converted into the corresponding esters. With sodium peroxide it turns into dibenzoyl peroxide , a radical initiator for polymerizations. However, the atom economy of these syntheses is poor, since stoichiometric amounts of salts are obtained.