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An oxide (/ ˈ ɒ k s aɪ d /) is a chemical compound containing at least one oxygen atom and one other element [1] in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of –2) of oxygen, an O 2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials ...
Download as PDF; Printable version; In other projects ... not pure elements in their standard state or allotropes. ... −1 +3 +5 11 [134] 112 copernicium: Cn +2 +4 12
Many oxyanions of elements in lower oxidation state obey the octet rule and this can be used to rationalize the formulae adopted. For example, chlorine(V) has two valence electrons so it can accommodate three electron pairs from bonds with oxide ions. The charge on the ion is +5 − 3 × 2 = −1, and so the formula is ClO − 3.
The −1 occurs because each carbon is bonded to one hydrogen atom (a less electronegative element), and the − 1 / 5 because the total ionic charge of −1 is divided among five equivalent carbons. Again this can be described as a resonance hybrid of five equivalent structures, each having four carbons with oxidation state −1 and ...
Compounds containing oxygen in other oxidation states are very uncommon: − 1 ⁄ 2 (superoxides), − 1 ⁄ 3 , 0 (elemental, hypofluorous acid), + 1 ⁄ 2 , +1 (dioxygen difluoride), and +2 (oxygen difluoride). Oxygen is reactive and will form oxides with all other elements except the noble gases helium, neon, argon and krypton. [1]
For cations that take on multiple charges, the charge is written using Roman numerals in parentheses immediately following the element name. For example, Cu(NO 3) 2 is copper(II) nitrate, because the charge of two nitrate ions (NO − 3) is 2 × −1 = −2, and since the net charge of the ionic compound must be zero, the Cu ion has a 2+ charge ...
When the electropositive element is a metal, the compounds are sometimes referred to as “metal-rich”. Thus the normal oxide of caesium is Cs 2 O, which is described as a Cs + salt of O 2− . A suboxide of caesium is Cs 11 O 3 , where the charge on Cs is clearly less than 1+, but the oxide is still described as O 2− .
Osmium dioxide is another known oxide of osmium, which can be obtained by the reaction of osmium with a variety of oxidizing agents, including, sodium chlorate, osmium tetroxide, and nitric oxide at about 600 °C. [18] [19] It does not dissolve in water, but is attacked by dilute hydrochloric acid. [20] [21] The crystals have rutile structure. [22]