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Pyrolysis of lignin from gymnosperms gives more guaiacol, resulting from removal of the propenyl group of coniferyl alcohol. These lignins are said to have a high guaiacyl (or G) content. In contrast, lignins derived from sinapyl alcohol affords syringol. A high syringyl (or S) content is indicative of lignin from angiosperms. [10]
Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. [1] Lignins are particularly important in the formation of cell walls , especially in wood and bark , because they lend rigidity and do not rot easily.
It is a colorless solid, although typical samples are brown owing to air-oxidized impurities. Together with guaiacol, syringol and its derivatives are produced by the pyrolysis of lignin. Specifically, syringol is derived from the thermal decomposition of the sinapyl alcohol component. As such, syringol is an important component of wood smoke.
Lignocellulose refers to plant dry matter , so called lignocellulosic biomass. It is the most abundantly available raw material on the Earth for the production of biofuels . [ 1 ] It is composed of two kinds of carbohydrate polymers, cellulose and hemicellulose , and an aromatic-rich polymer called lignin . [ 1 ]
Eugenol / ˈ j uː dʒ ɪ n ɒ l / is an allyl chain-substituted guaiacol, a member of the allylbenzene class of chemical compounds. [2] It is a colorless to pale yellow, aromatic oily liquid extracted from certain essential oils especially from clove, nutmeg, cinnamon, basil and bay leaf.
Lignin is a polymer with an inert nature that forms the structures of woody plants. The ratio of the three monolignols as well as their linkages varies depending on the plant species. For example, Norway spruce lignin is almost entirely derived from coniferyl alcohol, whereas paracoumaryl alcohol is the main monomer of lignin in grasses. [4]
[citation needed] Decomposition of dead plant material causes complex organic compounds to be slowly oxidized lignin-like humus or to break down into simpler forms (sugars and amino sugars, aliphatic and phenolic organic acids), which are further transformed into microbial biomass (microbial humus) or are reorganized, and further oxidized, into ...
Polyphenols, such as lignin, are larger molecules (macromolecules). Their upper molecular weight limit is about 800 daltons , which allows for the possibility to rapidly diffuse across cell membranes so that they can reach intracellular sites of action or remain as pigments once the cell senesces .
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