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Electronegativity (Pauling scale) → Atomic radius decreases → Ionization energy increases → Electronegativity increases →. There are no reliable sources for Pm, Eu and Yb other than the range of 1.1–1.2; see Pauling, Linus (1960). The Nature of the Chemical Bond. 3rd ed., Cornell University Press, p. 93.
The higher the associated electronegativity, the more an atom or a substituent group attracts electrons. Electronegativity serves as a simple way to quantitatively estimate the bond energy, and the sign and magnitude of a bond's chemical polarity, which characterizes a bond along the continuous scale from covalent to ionic bonding.
93. ^ The electronegativity of francium was chosen by Pauling as 0.7, close to that of caesium (also assessed 0.7 at that point). The base value of hydrogen was later increased by 0.10 and caesium's electronegativity was later refined to 0.79; however, no refinements have been made for francium as no experiment has been conducted.
Second rule: the electrostatic valence rule. For a given cation, Pauling defined [2] the electrostatic bond strength to each coordinated anion as , where z is the cation charge and ν is the cation coordination number. A stable ionic structure is arranged to preserve local electroneutrality, so that the sum of the strengths of the electrostatic ...
Linus Carl Pauling FRS (/ ˈpɔːlɪŋ / PAW-ling; February 28, 1901 – August 19, 1994) [ 4 ] was an American chemist, biochemist, chemical engineer, peace activist, author, and educator. He published more than 1,200 papers and books, of which about 850 dealt with scientific topics. [ 5 ] New Scientist called him one of the 20 greatest ...
There are two possible structures for hydrogen cyanide, HCN and CNH, differing only as to the position of the hydrogen atom. The structure with hydrogen attached to nitrogen, CNH, leads to formal charges of -1 on carbon and +1 on nitrogen, which would be partially compensated for by the electronegativity of nitrogen and Pauling calculated the net charges on H, N and C as -0.79, +0.75 and +0.04 ...
The electron affinity (Eea) of an atom or molecule is defined as the amount of energy released when an electron attaches to a neutral atom or molecule in the gaseous state to form an anion. X (g) + e − → X − (g) + energy. This differs by sign from the energy change of electron capture ionization. [1] The electron affinity is positive when ...
The chemical potential of a species in a mixture is defined as the rate of change of free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species ...