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  2. Chemical polarity - Wikipedia

    en.wikipedia.org/wiki/Chemical_polarity

    Examples of household nonpolar compounds include fats, oil, and petrol/gasoline. In the methane molecule (CH 4) the four C−H bonds are arranged tetrahedrally around the carbon atom. Each bond has polarity (though not very strong). The bonds are arranged symmetrically so there is no overall dipole in the molecule. The diatomic oxygen molecule ...

  3. Non-covalent interaction - Wikipedia

    en.wikipedia.org/wiki/Non-covalent_interaction

    The hydrophobic effect is the desire for non-polar molecules to aggregate in aqueous solutions in order to separate from water. [22] This phenomenon leads to minimum exposed surface area of non-polar molecules to the polar water molecules (typically spherical droplets), and is commonly used in biochemistry to study protein folding and other ...

  4. Molecular orbital diagram - Wikipedia

    en.wikipedia.org/wiki/Molecular_orbital_diagram

    The σ from the 2p is more non-bonding due to mixing, and same with the 2s σ. This also causes a large jump in energy in the 2p σ* orbital. The bond order of diatomic nitrogen is three, and it is a diamagnetic molecule. [12] The bond order for dinitrogen (1σ g 2 1σ u 2 2σ g 2 2σ u 2 1π u 4 3σ g 2) is three because two electrons are now ...

  5. Carbon–carbon bond - Wikipedia

    en.wikipedia.org/wiki/Carboncarbon_bond

    A carboncarbon bond is a covalent bond between two carbon atoms. [1] The most common form is the single bond : a bond composed of two electrons , one from each of the two atoms. The carboncarbon single bond is a sigma bond and is formed between one hybridized orbital from each of the carbon atoms.

  6. Neighbouring group participation - Wikipedia

    en.wikipedia.org/wiki/Neighbouring_group...

    In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.

  7. Lone pair - Wikipedia

    en.wikipedia.org/wiki/Lone_pair

    In Group 14 elements (the carbon group), lone pairs can manifest themselves by shortening or lengthening single bond (bond order 1) lengths, [16] as well as in the effective order of triple bonds as well. [17] [18] The familiar alkynes have a carbon-carbon triple bond (bond order 3) and a linear geometry of 180° bond angles (figure A in ...

  8. Lewis acids and bases - Wikipedia

    en.wikipedia.org/wiki/Lewis_acids_and_bases

    For example, carbon monoxide is a very weak Brønsted–Lowry base but it forms a strong adduct with BF 3. In another comparison of Lewis and Brønsted–Lowry acidity by Brown and Kanner, [ 19 ] 2,6-di- t -butylpyridine reacts to form the hydrochloride salt with HCl but does not react with BF 3 .

  9. SN2 reaction - Wikipedia

    en.wikipedia.org/wiki/SN2_reaction

    For example, 1-bromo-1-fluoroethane can undergo nucleophilic attack to form 1-fluoroethan-1-ol, with the nucleophile being an HO − group. In this case, if the reactant is levorotatory, then the product would be dextrorotatory, and vice versa. [3] S N 2 mechanism of 1-bromo-1-fluoroethane with one of the carbon atoms being a chiral centre.