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If multiple phases of matter are present, the chemical potentials across a phase boundary are equal. [8] Combining expressions for the Gibbs–Duhem equation in each phase and assuming systematic equilibrium (i.e. that the temperature and pressure is constant throughout the system), we recover the Gibbs' phase rule.
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
Josiah Willard Gibbs Born (1839-02-11) February 11, 1839 New Haven, Connecticut, U.S. Died April 28, 1903 (1903-04-28) (aged 64) New Haven, Connecticut, U.S. Nationality American Alma mater Yale College (BA, PhD) Known for List Statistical mechanics Chemical thermodynamics Chemical potential Cross product Dyadics Exergy Principle of maximum work Phase rule Phase space Physical optics Physics ...
Gibbs's paper marked the beginning of chemical thermodynamics by integrating chemical, physical, electrical, and electromagnetic phenomena into a coherent system. It introduced concepts such as chemical potential, phase rule, and more, which form the basis for modern physical chemistry.
Calculating the number of components in a system is necessary when applying Gibbs' phase rule in determination of the number of degrees of freedom of a system. The number of components is equal to the number of distinct chemical species (constituents), minus the number of chemical reactions between them, minus the number of any constraints ...
This equal area rule can also be derived by making use of the Helmholtz free energy. [24] In any event the Maxwell construction derives from the Gibbs condition of material equilibrium. However, even though g f = g g {\displaystyle g_{f}=g_{\text{g}}} is more fundamental it is more abstract than the equal area rule, which is understood ...
The theorem is Gibbs's phase rule, not Gibbs' phase rule. (In English, one leaves off the final s only when it's difficult to pronounce.) Gibb's phase rule first appeared in the Transactions of the Connecticut Academy of Sciences in the paper 'On the Equilibrium of . Heterogeneous Substances', published in parts between 1875 & 1878.
G = Gibbs free energy p = Pressure H = Enthalpy S = Entropy U = Internal energy V = Volume F = Helmholtz free energy T = Temperature. The thermodynamic square (also known as the thermodynamic wheel, Guggenheim scheme or Born square) is a mnemonic diagram attributed to Max Born and used to help determine thermodynamic relations.