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Stereochemistry focuses on stereoisomers, red boxes in the picture. In stereochemistry, stereoisomerism, or spatial isomerism, is a form of isomerism in which molecules have the same molecular formula and sequence of bonded atoms (constitution), but differ in the three-dimensional orientations of their atoms in space. [1][2] This contrasts with ...
Stereochemistry focuses on stereoisomers. Stereochemistry, a subdiscipline of chemistry, studies the spatial arrangement of atoms that form the structure of molecules and their manipulation. [1] The study of stereochemistry focuses on the relationships between stereoisomers, which by definition have the same molecular formula and sequence of ...
The atropisomer is an iodoaryl compound synthesised starting from (S)- valine and exists as the (M,S) isomer and the (P,S) isomer. The interconversion barrier between the two is 24.3 kcal / mol (101.7 kJ /mol). The (M,S) isomer can be obtained exclusively from this mixture by recrystallisation from hexanes.
Conformational isomerism. Rotation about single bond of butane to interconvert one conformation to another. The gauche conformation on the right is a conformer, while the eclipsed conformation on the left is a transition state between conformers. Above: Newman projection; below: depiction of spatial orientation.
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PDFtk. PDFtk (short for PDF Toolkit) is a toolkit for manipulating Portable Document Format (PDF) documents. [3][4] It runs on Linux, Windows and macOS. [5] It comes in three versions: PDFtk Server (open-source command-line tool), PDFtk Free (freeware) and PDFtk Pro (proprietary paid). [2] It is able to concatenate, shuffle, split and rotate ...
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