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Rydberg's formula as it appears in a November 1888 record. In atomic physics, the Rydberg formula calculates the wavelengths of a spectral line in many chemical elements. The formula was primarily presented as a generalization of the Balmer series for all atomic electron transitions of hydrogen. It was first empirically stated in 1888 by the ...
Atomic electron transition. An electron in a Bohr model atom, moving from quantum level n = 3 to n = 2 and releasing a photon. The energy of an electron is determined by its orbit around the atom. The n = 0 orbit, commonly referred to as the ground state, has the lowest energy of all states in the system. In atomic physics and chemistry, an ...
The 3→2 transition depicted here produces H-alpha, the first line of the Balmer series. For hydrogen ( Z = 1) this transition results in a photon of wavelength 656 nm (red). The Balmer series is characterized by the electron transitioning from n ≥ 3 to n = 2, where n refers to the radial quantum number or principal quantum number of the ...
Lyman series. In physics and chemistry, the Lyman series is a hydrogen spectral series of transitions and resulting ultraviolet emission lines of the hydrogen atom as an electron goes from n ≥ 2 to n = 1 (where n is the principal quantum number), the lowest energy level of the electron (groundstate). The transitions are named sequentially by ...
d electron count. The d electron count or number of d electrons is a chemistry formalism used to describe the electron configuration of the valence electrons of a transition metal center in a coordination complex. [1][2] The d electron count is an effective way to understand the geometry and reactivity of transition metal complexes.
Molecular electronic transition. In theoretical chemistry, molecular electronic transitions take place when electrons in a molecule are excited from one energy level to a higher energy level. The energy change associated with this transition provides information on the structure of the molecule and determines many of its properties, such as colour.
Fermi's golden rule. In quantum physics, Fermi's golden rule is a formula that describes the transition rate (the probability of a transition per unit time) from one energy eigenstate of a quantum system to a group of energy eigenstates in a continuum, as a result of a weak perturbation. This transition rate is effectively independent of time ...
[4] [5] Reverse electron transitions for all these types of excited molecules are also possible to return to their ground states, which can be designated as σ* → σ, π* → π, or π* → n. A transition in an energy level of an electron in a molecule may be combined with a vibrational transition and called a vibronic transition.