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In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.
A set of base units in the atomic system as in one proposal are the electron rest mass, the magnitude of the electronic charge, the Planck constant, and the permittivity. [6] [9] In the atomic units system, each of these takes the value 1; the corresponding values in the International System of Units [10]: 132 are given in the table.
The molecular mass (for molecular compounds) and formula mass (for non-molecular compounds, such as ionic salts) are commonly used as synonyms of molar mass, differing only in units (daltons vs g/mol); however, the most authoritative sources define it differently. The difference is that molecular mass is the mass of one specific particle or ...
The atomic mass of atoms, ions, or atomic nuclei is slightly less than the sum of the masses of their constituent protons, neutrons, and electrons, due to (per E = mc 2). Atomic mass is often measured in dalton (Da) or unified atomic mass unit (u). One dalton is equal to 1 ⁄ 12 the mass of a carbon-12 atom in its natural state.
The mass number (symbol A, from the German word: Atomgewicht, "atomic weight"), [1] also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is approximately equal to the atomic (also known as isotopic) mass of the atom expressed in atomic mass units.
For example, water has a molar mass of 18.0153(3) g/mol, but individual water molecules have molecular masses which range between 18.010 564 6863(15) Da (1 H 2 16 O) and 22.027 7364(9) Da (2 H 2 18 O). Atomic and molecular masses are usually reported in daltons, which is defined in terms of the mass of the isotope 12 C (carbon-12).
In 1803 John Dalton proposed to use the (still unknown) atomic mass of the lightest atom, hydrogen, as the natural unit of atomic mass. This was the basis of the atomic weight scale. [13] For technical reasons, in 1898, chemist Wilhelm Ostwald and others proposed to redefine the unit of atomic mass as 1 / 16 the mass of an oxygen atom. [14]
The dalton (symbol: Da) is the standard unit that is used for indicating mass on an atomic or molecular scale (atomic mass). [1] The unified atomic mass unit (symbol: u) is equivalent to the dalton. One dalton is approximately the mass of one a single proton or neutron. [2] The unified atomic mass unit has a value of 1.660 538 921 (73) × 10 ...