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The square wave in mathematics has many definitions, which are equivalent except at the discontinuities: It can be defined as simply the sign function of a sinusoid: = () = () = () = (), which will be 1 when the sinusoid is positive, −1 when the sinusoid is negative, and 0 at the discontinuities.
The time-independent Schrödinger equation for the wave function is ^ = [+ ()] = (), where Ĥ is the Hamiltonian, ħ is the reduced Planck constant, m is the mass, E the energy of the particle. The step potential is simply the product of V 0 , the height of the barrier, and the Heaviside step function : V ( x ) = { 0 , x < 0 V 0 , x ≥ 0 ...
Consequently, the wave function also became a four-component function, governed by the Dirac equation that, in free space, read (+ (= )) =. This has again the form of the Schrödinger equation, with the time derivative of the wave function being given by a Hamiltonian operator acting upon the wave function.
Functional approximation of square wave using 5 harmonics Functional approximation of square wave using 25 harmonics Functional approximation of square wave using 125 harmonics. The Gibbs phenomenon is a behavior of the Fourier series of a function with a jump discontinuity and is described as the following:
In classical wave-physics, this effect is known as evanescent wave coupling. The likelihood that the particle will pass through the barrier is given by the transmission coefficient, whereas the likelihood that it is reflected is given by the reflection coefficient. Schrödinger's wave-equation allows these coefficients to be calculated.
Consequently, the wave equation is approximated in the SVEA as: + = . It is convenient to choose k 0 and ω 0 such that they satisfy the dispersion relation: = . This gives the following approximation to the wave equation, as a result of the slowly varying envelope approximation:
A square wave (represented as the blue dot) is approximated by its sixth partial sum (represented as the purple dot), formed by summing the first six terms (represented as arrows) of the square wave's Fourier series. Each arrow starts at the vertical sum of all the arrows to its left (i.e. the previous partial sum).
In this case, the wave functions are square integrable. One can initially take the function space as the space of square integrable functions, usually denoted L 2. The displayed functions are solutions to the Schrödinger equation. Obviously, not every function in L 2 satisfies the Schrödinger equation for the hydrogen atom.