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In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
Name Formula Nitroxide: O=N − or NO −: Nitrite: O=N−O − or NO − 2: Nitrate: O 2 N−O − or NO − 3: Peroxynitrite: O=N−O−O − or NO − 3 ...
In water, nitric oxide reacts with oxygen to form nitrous acid (HNO 2). The reaction is thought to proceed via the following stoichiometry: 4 • NO + O 2 + 2 H 2 O → 4 HNO 2. Nitric oxide reacts with fluorine, chlorine, and bromine to form the nitrosyl halides, such as nitrosyl chloride: 2 • NO + Cl 2 → 2 NOCl
Oxidation numbers are assigned to elements in a molecule such that the overall sum is zero in a neutral molecule. The number indicates the degree of oxidation of each element caused by molecular bonding. In ionic compounds, the oxidation numbers are the same as the element's ionic charge.
NO y is the class of compounds comprising NO x and the NO z compounds produced from the oxidation of NO x which include nitric acid, nitrous acid (HONO), dinitrogen pentoxide (N 2 O 5), peroxyacetyl nitrate (PAN), alkyl nitrates (RONO 2), peroxyalkyl nitrates (ROONO 2), the nitrate radical (NO 3), and peroxynitric acid (HNO 4).
Nitrogen trioxide or nitrate radical is an oxide of nitrogen with formula NO 3, consisting of three oxygen atoms covalently bound to a nitrogen atom. This highly unstable blue compound has not been isolated in pure form, but can be generated and observed as a short-lived component of gas, liquid, or solid systems.
Sodium nitrate is a white deliquescent solid very soluble in water. It is a readily available source of the nitrate anion (NO 3 − ), which is useful in several reactions carried out on industrial scales for the production of fertilizers , pyrotechnics , smoke bombs and other explosives , glass and pottery enamels , food preservatives (esp ...
The formal oxidation state of the nitrogen atom in nitrite is +3. This means that it can be either oxidized to oxidation states +4 and +5, or reduced to oxidation states as low as −3. Standard reduction potentials for reactions directly involving nitrous acid are shown in the table below: [4]