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  2. Sigma-pi and equivalent-orbital models - Wikipedia

    en.wikipedia.org/wiki/Sigma-pi_and_equivalent...

    The σ-π model differentiates bonds and lone pairs of σ symmetry from those of π symmetry, while the equivalent-orbital model hybridizes them. The σ-π treatment takes into account molecular symmetry and is better suited to interpretation of aromatic molecules ( Hückel's rule ), although computational calculations of certain molecules tend ...

  3. Electronic properties of graphene - Wikipedia

    en.wikipedia.org/wiki/Electronic_properties_of...

    The graphene sheet thus displays a semimetallic (or zero-gap semiconductor) character. Two of the six Dirac points are independent, while the rest are equivalent by symmetry. In the vicinity of the K-points the energy depends linearly on the wave vector, similar to a relativistic particle.

  4. Sigma bond - Wikipedia

    en.wikipedia.org/wiki/Sigma_bond

    In chemistry, sigma bonds (σ bonds) or sigma overlap are the strongest type of covalent chemical bond. [1] They are formed by head-on overlapping between atomic orbitals along the internuclear axis. Sigma bonding is most simply defined for diatomic molecules using the language and tools of symmetry groups. In this formal approach, a σ-bond is ...

  5. List of formulae involving π - Wikipedia

    en.wikipedia.org/wiki/List_of_formulae_involving_π

    More formulas of this nature can be given, as explained by Ramanujan's theory of elliptic functions to alternative bases. Perhaps the most notable hypergeometric inversions are the following two examples, involving the Ramanujan tau function τ {\displaystyle \tau } and the Fourier coefficients j {\displaystyle \mathrm {j} } of the J-invariant ...

  6. Levi-Civita symbol - Wikipedia

    en.wikipedia.org/wiki/Levi-Civita_symbol

    In two dimensions, the Levi-Civita symbol is defined by: = {+ (,) = (,) (,) = (,) = The values can be arranged into a 2 × 2 antisymmetric matrix: = (). Use of the two-dimensional symbol is common in condensed matter, and in certain specialized high-energy topics like supersymmetry [1] and twistor theory, [2] where it appears in the context of 2-spinors.

  7. Machin-like formula - Wikipedia

    en.wikipedia.org/wiki/Machin-like_formula

    Machin-like formulas for π can be constructed by finding a set of integers , =, where all the prime factorisations of ⁠ + ⁠, taken together, use a number of distinct primes , and then using either linear algebra or the LLL basis-reduction algorithm to construct linear combinations of arctangents of . For example, in the Størmer formula ...

  8. Experimental uncertainty analysis - Wikipedia

    en.wikipedia.org/wiki/Experimental_uncertainty...

    For this simulation, a sigma of 0.03 seconds for measurements of T was used; measurements of L and θ assumed negligible variability. In the figure the widths of one-, two-, and three-sigma are indicated by the vertical dotted lines with the arrows.

  9. Sigma model - Wikipedia

    en.wikipedia.org/wiki/Sigma_model

    In physics, a sigma model is a field theory that describes the field as a point particle confined to move on a fixed manifold. This manifold can be taken to be any Riemannian manifold, although it is most commonly taken to be either a Lie group or a symmetric space.