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The steroids and sterols in animals are biologically produced from terpenoid precursors. Sometimes terpenoids are added to proteins, e.g., to enhance their attachment to the cell membrane; this is known as isoprenylation.
Biogenetic precursor of all indole alkaloids is the amino acid tryptophan. For most of them, the first synthesis step is decarboxylation of tryptophan to form tryptamine. Dimethyltryptamine (DMT) is formed from tryptamine by methylation with the participation of coenzyme of S-adenosyl methionine (SAM).
The term terpene was coined in 1866 by the German chemist August Kekulé to denote all hydrocarbons having the empirical formula C 10 H 16, of which camphene was one. Previously, many hydrocarbons having the empirical formula C 10 H 16 had been called "camphene", but many other hydrocarbons of the same composition had different names.
Isopentenyl pyrophosphate (IPP, isopentenyl diphosphate, or IDP) [1] is an isoprenoid precursor. IPP is an intermediate in the classical, HMG-CoA reductase pathway (commonly called the mevalonate pathway) and in the non-mevalonate MEP pathway of isoprenoid precursor biosynthesis.
Geranyl pyrophosphate is the precursor to monoterpenes (and hence monoterpenoids). [2] Elimination of the pyrophosphate group from geranyl pyrophosphate leads to the formation of acyclic monoterpenes such as ocimene and the myrcenes. Hydrolysis of the phosphate groups leads to the prototypical acyclic monoterpenoid geraniol.
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Squalene is a biochemical precursor to both steroids and hopanoids. [12] For sterols, the squalene conversion begins with oxidation (via squalene monooxygenase) of one of its terminal double bonds, resulting in 2,3-oxidosqualene.
GGPP is also the precursor for the synthesis of the phytane by the action of the enzyme geranylgeranyl reductase. This compound is used for the biosynthesis of tocopherols and the phytyl functional group is used in the formation of chlorophyll a , ubiquinones , plastoquinone and phylloquinone .