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Energy profile (chemistry) In theoretical chemistry, an energy profile is a theoretical representation of a chemical reaction or process as a single energetic pathway as the reactants are transformed into products. This pathway runs along the reaction coordinate, which is a parametric curve that follows the pathway of the reaction and indicates ...
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
Dielectric thermal analysis. Differential scanning calorimetry (DSC) is a thermoanalytical technique in which the difference in the amount of heat required to increase the temperature of a sample and reference is measured as a function of temperature. [1] Both the sample and reference are maintained at nearly the same temperature throughout the ...
An endothermic process is a chemical or physical process that absorbs heat from its surroundings. [1] In terms of thermodynamics, it is a thermodynamic process with an increase in the enthalpy H (or internal energy U) of the system. [2] In an endothermic process, the heat that a system absorbs is thermal energy transfer into the system.
Thermogenesis. v. t. e. An endotherm (from Greek ἔνδον endon "within" and θέρμη thermē "heat") is an organism that maintains its body at a metabolically favorable temperature, largely by the use of heat released by its internal bodily functions instead of relying almost purely on ambient heat. Such internally generated heat is ...
Potential energy surfaces are commonly shown as three-dimensional graphs, but they can also be represented by two-dimensional graphs, in which the advancement of the reaction is plotted by the use of isoenergetic lines. The collinear system H + H 2 is a simple reaction that allows a two-dimension PES to be plotted in an easy and understandable way.
v. t. e. The group that includes mammals and birds, both "warm-blooded" homeothermic animals (in red) is polyphyletic. Homeothermy, homothermy or homoiothermy[1] is thermoregulation that maintains a stable internal body temperature regardless of external influence. This internal body temperature is often, though not necessarily, higher than the ...
In chemistry, thermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components. [1] The term cycle is used because aside of water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled. If work is partially used as an input, the ...