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Lead perchlorate trihydrate is produced by the reaction of lead(II) oxide, lead carbonate, or lead nitrate by perchloric acid: . Pb(NO 3) 2 + HClO 4 → Pb(ClO 4) 2 + HNO 3. The excess perchloric acid was removed by first heating the solution to 125 °C, then heating it under moist air at 160 °C to remove the perchloric acid by converting the acid to the dihydrate.
Perchlorate compounds oxidize organic compounds, especially when the mixture is heated. The explosive decomposition of ammonium perchlorate is catalyzed by metals and heat. [13] As perchlorate is a weak Lewis base (i.e., a weak electron pair donor) and a weak nucleophilic anion, it is also a very weakly coordinating anion. [13]
Thus while carbon tetrachloride is a stable compound, with lead the oxidation state +2 is favored and PbCl 4 quickly becomes PbCl 2. Indeed, the inert pair effect causes lead to favor its +2 oxidation state: Pb atom loses all its outermost p electrons and ends up with a stable, filled s subshell. [7]
The compounds are almost insoluble in water, weak acids, and (NH 4) 2 S/(NH 4) 2 S 2 solution is the key for separation of lead from analytical groups I to III elements, tin, arsenic, and antimony. The compounds dissolve in nitric and hydrochloric acids, to give elemental sulfur and hydrogen sulfide, respectively. [ 7 ]
2 PbCl 2 + 4 RMgBr → R 4 Pb + Pb + 4 MgBrCl 3 PbCl 2 + 6 RMgBr → R 3 Pb-PbR 3 + Pb + 6 MgBrCl [12] These reactions produce derivatives that are more similar to organosilicon compounds, i.e. that Pb(II) tends to disproportionate upon alkylation. PbCl 2 can be used to produce PbO 2 by treating it with sodium hypochlorite (NaClO), forming a ...
The compound decomposes when heated to high temperatures and may explode if heated too strongly. Like most other perchlorates such as copper perchlorate and lead perchlorate , zinc perchlorate is prone to deliquescence .
Calcium perchlorate is a strong inorganic oxidizing agent, enhancing the combustion of other substances that can potentially lead to explosion. The perchlorate ion, ClO − 4, has a highly symmetrical tetrahedral structure that is strongly stabilized in solution by its low electron-donating proton-accepting power and its relatively low polarizability.
The need for dehydrating compounds has increased with the use of chemical reactions employing gases under pressure, as the water must be removed from the air prior to the reaction taking place. [ 8 ] Barium perchlorate is also used for the determination of small concentrations (down to 10 ppm, with an accuracy of +/- 1 ppm) of sulfate. [ 5 ]