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  2. Laws of thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Laws_of_thermodynamics

    The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships ...

  3. Third law of thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Third_law_of_thermodynamics

    The third law of thermodynamics states that the entropy of a system at absolute zero is a well-defined constant. This is because a system at zero temperature exists in its ground state, so that its entropy is determined only by the degeneracy of the ground state. In 1912 Nernst stated the law thus: "It is impossible for any procedure to lead to ...

  4. Thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Thermodynamics

    Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantities ...

  5. Thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_equations

    The law was actually the last of the laws to be formulated. First law of thermodynamics. d U = δ Q − δ W {\displaystyle dU=\delta Q-\delta W} where. d U {\displaystyle dU} is the infinitesimal increase in internal energy of the system, δ Q {\displaystyle \delta Q} is the infinitesimal heat flow into the system, and.

  6. Thermodynamic cycle - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_cycle

    t. e. A thermodynamic cycle consists of linked sequences of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the system to its initial state. [1] In the process of passing through a cycle, the ...

  7. Second law of thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Second_law_of_thermodynamics

    t. e. The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions. A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).

  8. Nernst heat theorem - Wikipedia

    en.wikipedia.org/wiki/Nernst_heat_theorem

    The Nernst heat theorem says that as absolute zero is approached, the entropy change Δ S for a chemical or physical transformation approaches 0. This can be expressed mathematically as follows: The above equation is a modern statement of the theorem. Nernst often used a form that avoided the concept of entropy. [1] Graph of energies at low ...

  9. Quantum thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Quantum_thermodynamics

    e. Quantum thermodynamics[1][2] is the study of the relations between two independent physical theories: thermodynamics and quantum mechanics. The two independent theories address the physical phenomena of light and matter. In 1905, Albert Einstein argued that the requirement of consistency between thermodynamics and electromagnetism [3] leads ...