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In thermodynamics, the compressibility factor (Z), also known as the compression factor or the gas deviation factor, describes the deviation of a real gas from ideal gas behaviour. It is simply defined as the ratio of the molar volume of a gas to the molar volume of an ideal gas at the same temperature and pressure .
The compressibility factor is defined as = where p is the pressure of the gas, T is its temperature, and is its molar volume, all measured independently of one another. In the case of an ideal gas, the compressibility factor Z is equal to unity, and the familiar ideal gas law is recovered:
In an oxygen system the presence of oxygen is implied, and in a sufficiently high partial pressure of oxygen, most materials can be considered fuel. Potential ignition sources are present in almost all oxygen systems, but fire hazards can be mitigated by controlling the risk factors associated with the oxygen, fuel, or heat, which can limit the ...
compressibility effects; variable specific heat capacity; van der Waals forces; non-equilibrium thermodynamic effects; issues with molecular dissociation and elementary reactions with variable composition; For most applications, such a detailed analysis is unnecessary, and the ideal gas approximation can be used with reasonable accuracy.
The general equation of state for a real gas is usually written as = = where the critical compressibility factor , which reflects the volumetric deviation of the real gases from the ideal gas, is also not easily accessible from laboratory experiments. However, critical pressure and critical temperature are more accessible from measurements.
the reaction rate is described by = [], where is a unimolecular rate constant. Since a reaction requires a change in molecular geometry, unimolecular rate constants cannot be larger than the frequency of a molecular vibration. Thus, in general, a unimolecular rate constant has an upper limit of k 1 ≤ ~10 13 s −1. For a bimolecular step
The limiting oxygen concentration (LOC), [1] also known as the minimum oxygen concentration (MOC), [2] is defined as the limiting concentration of oxygen below which combustion is not possible, independent of the concentration of fuel. It is expressed in units of volume percent of oxygen. The LOC varies with pressure and temperature.
An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. [1] The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is amenable to analysis under statistical mechanics.