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The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
When that same water then emerges from the tap, in time it comes into equilibrium with CO 2 levels in the air by outgassing its excess CO 2. The calcium carbonate becomes less soluble as a result, and the excess precipitates as lime scale. This same process is responsible for the formation of stalactites and stalagmites in limestone caves.
The temperature of the solution eventually decreases to match that of the surroundings. The equilibrium, between the gas as a separate phase and the gas in solution, will by Le Châtelier's principle shift to favour the gas going into solution as the temperature is decreased (decreasing the temperature increases the solubility of a gas).
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
CaCO 3 + 2 HCl → CaCl 2 + CO 2 + H 2 O. Thus, scale can be removed with acid. In solution the equilibrium between carbonate, bicarbonate, carbon dioxide and carbonic acid is sensitive to pH, temperature, and pressure. Although di- and trivalent carbonates have low solubility, bicarbonate salts are far more soluble.
It is also more soluble if the concentration of dissolved CO 2 is higher. Adding a reactant to the above chemical equation pushes the equilibrium towards the right producing more products: Ca 2+ and HCO 3 − , and consuming more reactants CO 2 and calcium carbonate according to Le Chatelier's principle .
Calcite exhibits an unusual characteristic called retrograde solubility: it is less soluble in water as the temperature increases. Calcite is also more soluble at higher pressures. [19] Pure calcite has the composition CaCO 3. However, the calcite in limestone often contains a few percent of magnesium. Calcite in limestone is divided into low ...
A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another.